127128-50-1

Basic information

• Product Name: FECATETRAENE-10
• Synonyms: FECATETRAENE-10
• CAS NO: 127128-50-1
• Molecular Formula: C13H20O3
• Molecular Weight: 224.298
• Mol File: 127128-50-1.mol

Chemical Properties

• Boiling Point: 404.7°Cat760mmHg
• Flash Point: 198.5°C
• Appearance: /
• Density: 1.022g/cm³
• Vapor Pressure: 3.11E-08mmHg at 25°C
• Refractive Index: 1.525
• CAS DataBase Reference: FECATETRAENE-10(CAS DataBase Reference)
• NIST Chemistry Reference: FECATETRAENE-10(127128-50-1)
• EPA Substance Registry System: FECATETRAENE-10(127128-50-1)

Safety Data

• Hazardous Substances Data: 127128-50-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H20O3/c1-2-3-4-5-6-7-8-9-10-16-12-13(15)11-14/h3-10,13-15H,2,11-12H2,1H3/b4-3-,6-5-,8-7-,10-9-

Upstream product

• 1576-87-0 trans-2-pentenal 
• 57018-53-8 (E,E,E)-2,4,6-nonatrienal 

Relevant articles and documents

Acid-catalyzed solvolysis of polyenol ethers. II. Effect of the degree of unsaturation

The acid-catalyzed solvolysis of polyenol ethers of glycerol gradually changes with increasing unsaturation from the regular pattern into an anomalous one in which hydroxy- and methoxy-substituted aldehydes are formed.

A CONVENIENT SYNTHESIS OF FECAPENTAENE-12 BY THE HORNER-WITTIG REACTION

A synthesis of racemic fecapentaene-12 and other glyceryl enol ethers has been developed based on the Horner-Wittig reaction.Coupling of the anion of the glyceryl substituted phosphine oxide 7 with unsaturated aldehydes 9a-c provided, after treatment with base, the silyl protected glyceryl enol ethers 11a-c.The silyl groups were easily removed and mixtures of E and Z isomers of glyceryl enol ethers 12a-c were obtained.The isomers could be separated upon washing with ether/hexane.