127140-75-4Relevant articles and documents
NON CONCERTED PATHWAY IN THE GENERATION OF DEHYDROARENES BY THERMAL DECOMPOSITION OF DIARYLIODONIUM CARBOXYLATES.
Luis, S. V.,Gavina, F.,Ferrer, P.,Safont, V. S.,Torres, M. C.,Burguete, M. I.
, p. 6281 - 6296 (2007/10/02)
1,3-Dehydrobenzene, 1,4-dehydrobenzene and 2,3-dehydronaphthalene are generated in the thermal decomposition of appropriate diaryliodonium carboxylates as demonstrated by the use of the three phase test.Intermediate species C6H4CO2 for m- and p-benzyne and C10H6CO2 for 2,3-naphthalyne have been unambiguously trapped in the same way, showing how non-concerted processes are the main pathway for generation of arynic intermediates from those iodonium salts.
