127421-35-6

Basic information

• Product Name: {Pd(H21C10OC6H3CH=NN=CHC6H4OC10H21)(μ-O2CC15H31)}2
• CAS NO: 127421-35-6
• Molecular Weight: 1763.26
• Mol File: 127421-35-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {Pd(H21C10OC6H3CH=NN=CHC6H4OC10H21)(μ-O2CC15H31)}2(CAS DataBase Reference)
• NIST Chemistry Reference: {Pd(H21C10OC6H3CH=NN=CHC6H4OC10H21)(μ-O2CC15H31)}2(127421-35-6)
• EPA Substance Registry System: {Pd(H21C10OC6H3CH=NN=CHC6H4OC10H21)(μ-O2CC15H31)}2(127421-35-6)

Safety Data

• Hazardous Substances Data: 127421-35-6(Hazardous Substances Data)

Upstream product

• 408-35-5 sodium palmitate 

Relevant articles and documents

Synthesis, characterization, and X-ray studies of nonplanar mesogens: Carboxylato-bridged orthopalladated azine complexes

The family of book-shaped orthopalladated dimers [Pd(H21C10OC6H3CH=NN=CHC 6H4OC10H21)(μ-O 2CCnH2n+1)]2 (n = 0-11, 13, 15, 17), which show mesogenic behavior influenced by the length of the bridging carboxylate, have been prepared. The shortest (n = 1-3) and longest (n ≥ 10) carboxylates give rise to more ordered mesophases and wider ranges of mesogenic behavior than the carboxylates of medium length. This is interpreted as a consequence of the molecular packing being disturbed on changing from short to medium chains and facilitated again when the carboxylate chains are long enough to situate themselves parallel to the azine chains. X-ray diffraction studies on monodomains give evidence of a peculiar molecular packing in these mesophases: some palladium-palladium correlations are found, which indicate the tendency to both a lateral association and a longitudinal shifting between neighboring molecules.