129006-48-0

Basic information

• Product Name: 5,10,15,20-tetra(2,4,6-trimethylphenyl)octabromoporphyrin
• Synonyms: 5,10,15,20-tetra(2,4,6-trimethylphenyl)octabromoporphyrin
• CAS NO: 129006-48-0
• Molecular Weight: 1414.24
• Mol File: 129006-48-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5,10,15,20-tetra(2,4,6-trimethylphenyl)octabromoporphyrin(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15,20-tetra(2,4,6-trimethylphenyl)octabromoporphyrin(129006-48-0)
• EPA Substance Registry System: 5,10,15,20-tetra(2,4,6-trimethylphenyl)octabromoporphyrin(129006-48-0)

Safety Data

• Hazardous Substances Data: 129006-48-0(Hazardous Substances Data)

Upstream product

• 56396-12-4 5,10,15,20-tetramesitylporphyrin 

Downstream Products

• 129006-49-1 meso-tetrakis-(3,5-disulfonatomesityl)-β-octabromoporphyrin 

Relevant articles and documents

CATALYTIC ACTIVITY AND CHEMICAL STABILITY OF PERHALOGENATED Mn(III)-TETRAARYLPORPHYRINS IN ALKENE EPOXIDATIONS

Structural factors, which govern the chemical stability of metallo-tetraaryl porphyrins, were investigated in CH2Cl2/H2O two-phase alkene epoxidations promoted by aqueous NaOCl or 30percent H2O2. In contrast to recent literature reports, the perhalogenati

Highly selective bromination of tetramesitylporphyrin: An easy access to robust metalloporphyrins, M-Br8TMP and M-Br8TMPS

The N-bromosuccinimide bromination of the zinc derivative of meso-tetramesitylporphyrin, Zn(TMP), in methanol at reflux in air, gives the corresponding (β-pyrrole)octabromo derivative, meso-tetramesityl-β-octabromoporphyrinatozinc, Zn(Br8TMP), in high yield (60-75%). Furthermore, the sulfonation by oleum of the metal-free ligand gives the persulfonated porphyrin, meso-tetrakis(3,5-disulfonatomesityl)-β-octabromoporphyrin, Br8 TMPSH2 (70-75%). These robust manganese and iron derivatives are efficient catalysts in oxygen atom or electron transfer reactions.