13012-54-9Relevant articles and documents
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Hall,D.N.
, p. 2082 - 2087 (1967)
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Preparation of ω-tetrahydropyran-2-ylsulfanylalkylmagnesium chlorides: Useful reagents for the synthesis of 1-(ω-mercaptoalkyl)-1,2- dihydrobuckminsterfullerenes (C60)
Kim, Sung Hoon,Lee, Sung Han,Kang, Seung Hoon
, p. 9693 - 9696 (1998)
ω-Tetrahydropyran-2-ylsulfanylalkylmagnesium chlorides are prepared as Grignard reagents containing protected mercaptoalkyl chains, which are useful for the direct introduction of ω-mercaptoalkyl chains to electrophiles. In order to prove the usefulness of these reagents, they were reacted with buckminsterfullerene (C60) to give 1-(ω-mercaptoalkyl)-1,2- dihydrobuckminsterfullerenes after the deprotection of THP group with TFA.