13030-09-6

Basic information

• Product Name: L-Glutamic acid alpha-benzyl ester
• Synonyms: A-BENZYL-L-GLUTAMATE;L-GLUTAMIC ACID ALPHA-BENZYL ESTER;L-ALPHA-BENZYL GLUTAMATE;H-GLU-OBZL;GLUTAMIC ACID-OBZL;1-benzyl l-glutamate;l-glutamic acid 1-benzyl ester;H-L-Glu-OBzl
• CAS NO: 13030-09-6
• Molecular Formula: C₁₂H₁₅NO₄
• Molecular Weight: 237.25
• Product Categories: Amino Acid Derivatives;Amino Acids;Glutamic acid [Glu, E];Amino Acids and Derivatives;Amino Acid Benzyl Esters;Amino Acids (C-Protected);Biochemistry;Amino Acid Derivatives
• Mol File: 13030-09-6.mol

Chemical Properties

• Melting Point: 157 °C
• Boiling Point: 416 °C at 760 mmHg
• Flash Point: 205.4 °C
• Appearance: /
• Density: 1.245 g/cm³
• Vapor Pressure: 1.15E-07mmHg at 25°C
• Refractive Index: 1.555
• Storage Temp.: -15°C
• PKA: 4.21±0.10(Predicted)
• CAS DataBase Reference: L-Glutamic acid alpha-benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: L-Glutamic acid alpha-benzyl ester(13030-09-6)
• EPA Substance Registry System: L-Glutamic acid alpha-benzyl ester(13030-09-6)

Safety Data

• Hazardous Substances Data: 13030-09-6(Hazardous Substances Data)

Usage

Chemical Properties

White solid

InChI:InChI=1/C12H15NO4/c13-10(6-7-11(14)15)12(16)17-8-9-4-2-1-3-5-9/h1-5,10H,6-8,13H2,(H,14,15)/t10-/m0/s1

Upstream product

• 2768-50-5 dibenzyl L-glutamate 
• 56-86-0 L-glutamic acid 
• 100-51-6 benzyl alcohol 
• 30924-93-7 Boc-Glu-OBn 
• 73469-43-9 dibenzyl N-trityl-(S)-glutamate 
• 73488-68-3 Tr-L-Glu(OBzl)-OH 
• 3705-42-8 Cbz-(L)-Glu-OBn 

Downstream Products

• 4491-17-2 N-(N-benzyloxycarbonyl-L-γ-glutamyl)-L-glutamic acid-1-benzyl ester 
• 3705-42-8 Cbz-(L)-Glu-OBn 
• 62188-74-3 H-Glu(O-t-Bu)-OBzl 
• 30924-93-7 Boc-Glu-OBn 
• 79974-14-4 N-<4-<<(benzyloxy)carbonyl>methylamino>benzoyl>-L-glutamic acid α-benzyl ester 
• 142982-01-2 N-<(R)-3-(benzyloxy)tetradecanoyl>-(S)-glutamic acid α-benzyl ester 
• 212777-14-5 2-(8-methoxycarbonyloxy-2,4-dioxo-4H-benzo[e][1,3]oxazin-3-yl)-pentanedioic acid 1-benzyl ester 
• 439152-22-4 1-benzyl N-[N^2',N^6'-bis(2,3-diacetoxybenzoyl)-L-lysyl]-L-glutamate 
• 840525-19-1 α-benzyl N-[N-(N-benzyloxycarbonyl-glycyl)-L-prolyl]-L-glutamate 
• 866139-30-2 (S)-2-pyrrol-1-yl-pentanedioic acid 1-benzyl ester 
• 883977-43-3 (S)-5-(benzyloxy)-4-(9H-carbazol-9-yl)-5-oxopentanoic acid 
• 1116-22-9 γ-L-glutamyl-L-glutamic acid 
• 115919-04-5 N-(N-benzyloxycarbonyl-O-methyl-L-γ-glutamyl)-L-glutamic acid-5-methyl ester 
• 124227-54-9 N-(N-benzyloxycarbonyl-O-methyl-L-γ-glutamyl)-1-thio-L-glutamic acid-5-methyl ester-S-phenyl ester 

Relevant articles and documents

High selective autocatalytic esterification of glutamic acid by benzyl alcohol with CuCl2 promoting

We found that the esterification of l-glutamic acid by benzyl alcohol is greatly promoted by CuCl2 even in H2O solvent, and the selectivity and yield of γ-benzyl ester of l-glutamic acid achieved 100% and 95.31%. Metal cation coordin

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