130782-68-2Relevant articles and documents
Palladium-catalyzed insertion reactions of isocyanides into thiocarbamates and selenocarbamates
Shiro, Daisuke,Fujiwara, Shin-Ichi,Tsuda, Susumu,Iwasaki, Takanori,Kuniyasu, Hitoshi,Kambe, Nobuaki
, p. 465 - 467 (2015)
The insertion reaction of isocyanides with thiocarbamates and selenocarbamates in the presence of a Pd(0) catalyst to selectively give 2-oxoethanimidothioates and -selenoates is reported. This is the first example of the insertion of an isocyanide into a
AlCl3-promoted thiolation of acyl C-H bonds with arylsulfonyl hydrazides
Chen, Jie,Mao, Jincheng,He, Yue,Shi, Daqing,Zou, Binyang,Zhang, Guoqi
supporting information, p. 9496 - 9500 (2015/11/18)
AlCl3-promoted thiolation of acyl C-H bonds with arylsulfonyl hydrazides was developed, which represents an effective synthesis of S-aryl thiocarbamates via C-S bond formation reaction.
The Newman-Kwart rearrangement re-evaluated by microwave synthesis
Moseley, Jonathan D.,Sankey, Rosalind F.,Tang, Olivier N.,Gilday, John P.
, p. 4685 - 4689 (2007/10/03)
The Newman-Kwart rearrangement (NKR) has been re-evaluated by microwave heating. Microwave technology has proven to be ideal for investigating this high temperature rearrangement and facilitated the confirmation of many aspects of this valuable reaction.