13153-92-9

Basic information

• Product Name: Phosphine sulfide, methylphenylpropyl-, (R)-
• CAS NO: 13153-92-9
• Molecular Formula: C10H15PS
• Molecular Weight: 198.269
• Mol File: 13153-92-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Phosphine sulfide, methylphenylpropyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine sulfide, methylphenylpropyl-, (R)-(13153-92-9)
• EPA Substance Registry System: Phosphine sulfide, methylphenylpropyl-, (R)-(13153-92-9)

Safety Data

• Hazardous Substances Data: 13153-92-9(Hazardous Substances Data)

Upstream product

• 72315-67-4 methylthio-methyl-n-propylphenylphosphonium trifluoromethanesulfonate 
• 87152-18-9 (+)R-methyl-n-propylphenylmethylselenophosphonium triflate 
• 17170-48-8 (R)-(+)-methylphenyl-n-propylphosphine oxide 
• 33995-97-0 (+)-(R)-methyl-n-propylphenylphosphine selenide 
• 701-03-1 (+)-(S)-methyl-n-propyl phenylphosphine 
• 34641-79-7 (+)R-methyl-n-propylphenylphosphine selenide 
• 425-75-2 trifluoromethanesulfonic acid ethyl ester 
• 1707-00-2 dimethylphenylphosphine sulfide 
• 701-03-1 (-)-(R)-methyl-n-propylphenylphosphine 

Downstream Products

• 701-03-1 (+)-(S)-methyl-n-propyl phenylphosphine 
• 1515-99-7 (S)-(-)-Methylphenyl-n-propylphosphanoxid 
• 17170-48-8 (R)-(+)-methylphenyl-n-propylphosphine oxide 
• 4653-63-8 methyl-phenyl-propyl-phosphine oxide 
• 701-03-1 methylpropylphenylphosphine 
• 72315-67-4 methylthio-methyl-n-propylphenylphosphonium trifluoromethanesulfonate 

Relevant articles and documents

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A new, stereoselective interconversion of phosphinothio-phosphinoseleno compounds, reduction of phosphinoseleno derivatives and retro pishchimuka rearrangement based on methylthio- and methylselenophosphonium salts chemistry

The interconversion of thiono- into seleno compounds was found to proceed with retention of the configuration at phosphorus and the mechanistic course of this process has been proposed. The isomerization reaction of phosphinothiolates into thiono-isomers via the phosphonium salts has been developed and considered as the "retro Pishchimuka" rearrangement.

Stereospecific Synthesis of Diastereoisomerically Pure (-)-(RP)-O-Mentyl Methylphenylphosphinite and Ethylphenylphosphinite: Key Intermediates in Synthesis of Chiral Tertiary Phosphines

The reaction of the diastereoisomerically pure (-)-(RP)-O-mentyl methylphenylphosphinite (9) and (-)-(RP)-O-mentyl ethylphenylphosphinite (2) with organolithium reagents has been found to give chiral tertiary phosphines (10) and (11) with a very high optical purity.