13232-08-1

Basic information

• Product Name: Phosphoric acid, 1,1-dimethylethyl diethyl ester
• CAS NO: 13232-08-1
• Molecular Formula: C8H19O4P
• Molecular Weight: 210.21
• Mol File: 13232-08-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Phosphoric acid, 1,1-dimethylethyl diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphoric acid, 1,1-dimethylethyl diethyl ester(13232-08-1)
• EPA Substance Registry System: Phosphoric acid, 1,1-dimethylethyl diethyl ester(13232-08-1)

Safety Data

• Hazardous Substances Data: 13232-08-1(Hazardous Substances Data)

Upstream product

• 507-40-4 tert-butylhypochlorite 
• 14540-22-8 diethyl (tert-butyl) phosphite 
• 63873-21-2 O,O-diethyl-S-isopropyl phosphorothiolate 
• 75-65-0 tert-butyl alcohol 
• 2404-05-9 O,O-diethyl S-methyl phosphorothioate 
• 762-04-9 phosphonic acid diethyl ester 

Downstream Products

• 598-02-7 Diethyl phosphate 
• 51761-27-4 diethyl phosphorobromidate 
• 594-34-3 1,2-dibromo-2-methyl-propane 
• 1623-14-9 ethyl phosphate 

Relevant articles and documents

Synthesis of Mixed Trialkyl Phosphates: Oxidative Phosphorylation of Alcohols with Dialkyl Phosphonates in the Presence of Copper(II) Chloride

Mixed trialkyl phosphonates were synthesized by oxidative phosphorylation of alcohols with dialkyl phosphonates and oxygen in the presence of copper(II) chloride in fairly good yields.

REACTION OF PROPOSED PHOSPHOROTHIOLATE S-OXIDE INTERMEDIATES WITH ALCOHOLS

S-Oxide 2 is an extremely reactive intermediate.Its phosphorylation vs rearrangement rates, strongly depend upon the nature of the nucleophile.