13249-59-7

Basic information

• Product Name: 2-bromo-N,N-diethylprop-2-en-1-amine
• CAS NO: 13249-59-7
• Molecular Formula: C₇H₁₄BrN
• Molecular Weight: 192.0968
• Mol File: 13249-59-7.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 171.6°C at 760 mmHg
• Flash Point: 57.6°C
• Density: 1.205g/cm³
• Vapor Pressure: 1.39mmHg at 25°C
• Refractive Index: 1.482
• CAS DataBase Reference: 2-bromo-N,N-diethylprop-2-en-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-N,N-diethylprop-2-en-1-amine(13249-59-7)
• EPA Substance Registry System: 2-bromo-N,N-diethylprop-2-en-1-amine(13249-59-7)

Safety Data

• Hazardous Substances Data: 13249-59-7(Hazardous Substances Data)

Upstream product

• 109-89-7 diethylamine 
• 513-31-5 2-bromoallyl bromide 

Downstream Products

• 19759-94-5 1-(3-diethylamino-prop-1-ynyl)-cyclohexanol 
• 92030-78-9 3-Diaethylamino-2-<1-hydroxy-cyclohexyl>-propen-(1) 
• 92725-41-2 1-Diaethylamino-3-phenyl-2-methylen-butanol-⁽³⁾ 
• 127998-34-9 4-(N,N-diethylamino)-3-methylene-1-phenyl-1-butanol 
• 66894-62-0 diethyl-oct-2-ynyl-amine 
• 19689-20-4 N,N-diethylhept-2-yn-1-amine 
• 500298-50-0 diethyl-hex-2-ynyl-amine 
• 73117-10-9 N,N-diethyl-2-butin-1-ylamine 
• 6323-82-6 but-2-ynyldiethylamine 
• 73350-31-9 3-cyclohexenyl-N,N-diethylprop-2-yn-1-amine 
• 133733-67-2 dimethyl 4-diethylaminomethyl-4-cyclohexene-cis-1,2-dicarboxylate 
• 133733-67-2 dimethyl 4-diethylaminomethyl-4-cyclohexene-trans-1,2-dicarboxylate 
• 133733-69-4 dimethyl 4-diethylaminomethyl-1,4-cyclohexadiene-1,2-dicarboxylate 
• 94911-23-6 3-Diaethylamino-1,1-diphenyl-2-methylen-propanol-⁽¹⁾ 

Relevant articles and documents

Selective Mono- and Polymethylene Homologations of Copper Reagents Using (Iodomethyl)zinc Iodide

A wide range of unsaturated aryl-, alkenyl-, alkynylcopper compounds can be selectively homologated by a methylene unit using (iodomethyl)zinc iodide or bis(iodomethyl)zinc.These reactions allow the generation of mixed allylic zinc-copper compounds which can be efficiently trapped with carbonyl compounds.An application to a general preparation of functionalized α-methylene-γ-butyrolactones is described.The homologation of alkynylcoppers with (iodomethyl)zinc iodide allows a one-pot preparation of propargylic copper reagents which in the presence of a carbonyl compound provide various homopropargylic alcohols in excellent yields.In the absence of an electrophile, a clean quadruple methylene homologation of alkynylcoppers occurs to furnish dienic copper reagents.The homologation of other types of copper reagents is also possible, and carbanions at the α-position to amines as well as homoenolates of aldehydes or ketones can also be prepared by this method.