132786-31-3

Basic information

• Product Name: 2-(1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-6-iodo-hexylsulfanyl)-benzothiazole
• Synonyms: 2-(1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-6-iodo-hexylsulfanyl)-benzothiazole
• CAS NO: 132786-31-3
• Molecular Weight: 593.199
• Mol File: 132786-31-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-6-iodo-hexylsulfanyl)-benzothiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-6-iodo-hexylsulfanyl)-benzothiazole(132786-31-3)
• EPA Substance Registry System: 2-(1,1,2,2,3,3,4,4,5,5,6,6-Dodecafluoro-6-iodo-hexylsulfanyl)-benzothiazole(132786-31-3)

Safety Data

• Hazardous Substances Data: 132786-31-3(Hazardous Substances Data)

Upstream product

• 375-80-4 dodecafluoro-1,6-diiodohexane 
• 149-30-4 2-Mercaptobenzothiazole 

Relevant articles and documents

PERFLUOROALKYLATION OF 2-MERCAPTOBENZOTHIAZOLE AND ITS ANALOGUES WITH PERFLUOROALKYL IODIDES BY AN SRN1 REACTION

The thiolates, generated in situ by the reaction of 2-mercaptobenzothiazole (1) and its analogues (2) and (3) with sodium hydride, react under UV irradiation with perfluoroalkyl iodides (4)-(8) to give the corresponding heteroaromatic perfluoroalkyl sulfides (9)-(18) in 50-98percent yields.The fact that the UV irradiation increases the conversion of perfluoroalkyl iodides and that the radical scavenger di-tert-butylnitroxide suppresses the reaction demonstrates that the reaction proceeds via an SRN1 mechanism.