132927-86-7Relevant articles and documents
Medium and Large N-Heterocycle Formation via Allene Hydroamination with a Bimetallic Rh(II) Catalyst
Bohman, Benjamin O.,Davis, Rhen C.,Forson, Kelton G.,McKnight, Caitlyn E.,Michaelis, David J.,Owens, Rachel N.,Smith, Stacey J.,Stillwell, Lillian R.,Wayment, Coriantumr Z.
, p. 63 - 68 (2022/01/19)
We report the synthesis of a 2-phosphinoimidazole-derived bimetallic Rh(II) complex that enables intramolecular allene hydroamination to form 7- to 10-member rings in high yield. Monometallic Rh complexes, in contrast, fail to achieve any product formatio
Electrophile-mediated Cyclisations involving the Allene ?-System. Stereoselectivity and Synthetic Utility of PdII-Catalysed Heteroatom Cyclisation Reactions. X-Ray Molecular Structure of Methyl 2-
Gallagher, Timothy,Davies, Ian W.,Jones, Stephen W.,Lathbury, David,Mahon, Mary F.,et al.
, p. 433 - 440 (2007/10/02)
PdII-mediated cyclisation and methoxycarbonylation of the phenyl-substituted allenic sulfonamides 4, 5 and 6 gave the corresponding N-sulfonyl 2,3-, 2,4- and 2,5-disubstituted pyrrolidines 9, 10 and 11, respectively.With the exception of compou
Gallagher, Timothy,Davies, Ian W.,Jones, Stephen W.,Lathbury, David,Mahon, Mary F.,et al.
, p. 433 - 440 (2007/10/02)
PdII-mediated cyclisation and methoxycarbonylation of the phenyl-substituted allenic sulfonamides 4, 5 and 6 gave the corresponding N-sulfonyl 2,3-, 2,4- and 2,5-disubstituted pyrrolidines 9, 10 and 11, respectively.With the exception of compou