13330-96-6Relevant articles and documents
Synthesis and pharmacological effects of bis-trialkylammonium alkanol carbonates.
POHORYLES,WISLICKI,SAREL
, p. 348 - 351 (1962)
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Budzikiewicz,Pesch
, p. 861,875 (1974)
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Enhanced product selectivity in continuous N-methylation of amino alcohols over solid acid-base catalysts with supercritical methanol
Oku, Tomoharu,Ikariya, Takao
, p. 3476 - 3479 (2007/10/03)
The unique properties of supercritical fluids can be exploited for fine-tuning product selectivity. Under the conditions listed for the N-methylation of amino alcohols (see scheme) over solid acid-base bifunctional catalysts, the total yield and product selectivity could be improved. Enhanced product selectivity might be attributed to the milder reaction conditions possible with supercritical methanol, as well as the increased concentration of methanol on the catalyst.
Addition-Rearrangement Reactions of N-(Arylsulphonyloxy)amines and 3,4-Dihydro-2H-pyran
Hoffman, Robert V.,Salvador, James M.
, p. 1375 - 1380 (2007/10/02)
A series of N-alkyl-O-(arylsulphonyl)hydroxylamines (NSA) was treated with 3,4-dihydro-2H-pyran (DHP).Acid-catalysed addition to the double bond followed by cationic rearrangement gave cyclic imidates from hydride migration (major) and ring expansion (min