13361-98-3Relevant articles and documents
Fluoro-Substituted Methyllithium Chemistry: External Quenching Method Using Flow Microreactors
Colella, Marco,Degennaro, Leonardo,Higuma, Ryosuke,Ishikawa, Susumu,Luisi, Renzo,Nagaki, Aiichiro,Takahashi, Yusuke,Tota, Arianna
supporting information, p. 10924 - 10928 (2020/05/08)
The external quenching method based on flow microreactors allows the generation and use of short-lived fluoro-substituted methyllithium reagents, such as fluoromethyllithium, fluoroiodomethyllithium, and fluoroiodostannylmethyllithium. Highly chemoselective reactions have been developed, opening new opportunities in the synthesis of fluorinated molecules using fluorinated organometallics.
Group 4 Organometallic Compounds. Part 8. Preparation and Moessbauer Spectra of Five- and Six-co-ordinate Di- and Tri-organotin Compounds containing Mixed Phenyl and Butyl Groups on Tin
Das, V. G. Kumar,Weng, Ng Seik,Smith, Peter J.,Hill, Robin
, p. 552 - 558 (2007/10/02)
Moessbauer spectroscopic data and preparative details are reported for a range of IVBuPh>, IVBu2Ph>, and IVBuPh2> compounds.The stereochemical preferences of the butyl and phenyl groups in octahedral and trigonal-