134023-32-8

Basic information

• Product Name: (3S,6R)-6-(2,2-Diphenylethenyl)-3,4-trimethylene-2,5-piperazinedione
• CAS NO: 134023-32-8
• Molecular Weight: 332.402
• Mol File: 134023-32-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3S,6R)-6-(2,2-Diphenylethenyl)-3,4-trimethylene-2,5-piperazinedione(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,6R)-6-(2,2-Diphenylethenyl)-3,4-trimethylene-2,5-piperazinedione(134023-32-8)
• EPA Substance Registry System: (3S,6R)-6-(2,2-Diphenylethenyl)-3,4-trimethylene-2,5-piperazinedione(134023-32-8)

Safety Data

• Hazardous Substances Data: 134023-32-8(Hazardous Substances Data)

Upstream product

• 205875-03-2 2-[((S)-1-tert-Butoxycarbonyl-pyrrolidine-2-carbonyl)-amino]-malonic acid dimethyl ester 
• 205875-05-4 (3S,6RS)-6-carboxy-1,3-trimethylene-2,5-piperazinedione 
• 205875-04-3 methyl 1,4-dioxoperhydropyrrolo[1,2-a]pyrazine-3-carboxylate 
• 134023-30-6 Boc-L-Pro-Gly(OMe)-OMe 
• 34290-72-7 tert-butyloxycarbonyl-prolyl-glycine methyl ester 
• 15761-39-4 1-(tert-butoxycarbonyl)-L-proline 
• 530-48-3 1,1-Diphenylethylene 
• 205875-06-5 (3RS,6S)-3-methoxy-1,6-trimethylene-2,5-piperazinedione 

Relevant articles and documents

Electrogenerated chiral building blocks for diastereoselective amidoalkylation reactions

Three different electrochemical methods have been applied for the synthesis of chiral building blocks for diastereoselective amidoalkylation reactions. These are A. the direct anodic α-methoxylation of amides and carbamates; B. anodic methoxylative decarboxylation of α-amino acid derivatives (Hofer-Moest reaction) C. indirect NaCl mediated anodic α-methoxylation of α-amino acid derivatives. The application of these building blocks for the synthesis of enantiomerically pure α-amino acids, dichiral 1,2-amino alcohols and chiral 1,3-diamines is described.