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13453-69-5

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13453-69-5 Usage

General Description

Lithium metaborate is a lithium salt of boric acid with the chemical formula LiBO2. It is commonly used in analytical chemistry as a flux and fusion reagent for preparing samples for X-ray fluorescence and inductively coupled plasma analysis. It has a high melting point and is stable at high temperatures, making it suitable for use in the preparation of solid samples for analysis. Lithium metaborate is also used in the production of specialty glasses and ceramics, as well as in the synthesis of other lithium compounds. Moreover, it is known for its low toxicity and high solubility in water, making it a versatile and valuable chemical compound in various industries.

Check Digit Verification of cas no

The CAS Registry Mumber 13453-69-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,4,5 and 3 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 13453-69:
(7*1)+(6*3)+(5*4)+(4*5)+(3*3)+(2*6)+(1*9)=95
95 % 10 = 5
So 13453-69-5 is a valid CAS Registry Number.
InChI:InChI=1/BO2.Li/c2-1-3;/q-1;+1

13453-69-5 Well-known Company Product Price

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  • Alfa Aesar

  • (10739)  Lithium metaborate, Puratronic?, 99.997% (metals basis)   

  • 13453-69-5

  • 25g

  • 461.0CNY

  • Detail
  • Alfa Aesar

  • (10739)  Lithium metaborate, Puratronic?, 99.997% (metals basis)   

  • 13453-69-5

  • 100g

  • 1571.0CNY

  • Detail
  • Alfa Aesar

  • (10739)  Lithium metaborate, Puratronic?, 99.997% (metals basis)   

  • 13453-69-5

  • 500g

  • 7040.0CNY

  • Detail
  • Alfa Aesar

  • (36760)  Lithium metaborate, ACS, 98.0-102.0%   

  • 13453-69-5

  • 50g

  • 265.0CNY

  • Detail
  • Alfa Aesar

  • (36760)  Lithium metaborate, ACS, 98.0-102.0%   

  • 13453-69-5

  • 250g

  • 1323.0CNY

  • Detail
  • Alfa Aesar

  • (12591)  Lithium metaborate, anhydrous, 99.9% (metals basis)   

  • 13453-69-5

  • 50g

  • 479.0CNY

  • Detail
  • Alfa Aesar

  • (12591)  Lithium metaborate, anhydrous, 99.9% (metals basis)   

  • 13453-69-5

  • 250g

  • 1464.0CNY

  • Detail
  • Alfa Aesar

  • (12591)  Lithium metaborate, anhydrous, 99.9% (metals basis)   

  • 13453-69-5

  • 1kg

  • 4537.0CNY

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  • Alfa Aesar

  • (32576)  Lithium metaborate, anhydrous, tech.   

  • 13453-69-5

  • 100g

  • 348.0CNY

  • Detail
  • Alfa Aesar

  • (32576)  Lithium metaborate, anhydrous, tech.   

  • 13453-69-5

  • 500g

  • 1381.0CNY

  • Detail
  • Alfa Aesar

  • (A16145)  Lithium metaborate, dried, 99%   

  • 13453-69-5

  • 25g

  • 168.0CNY

  • Detail
  • Alfa Aesar

  • (A16145)  Lithium metaborate, dried, 99%   

  • 13453-69-5

  • 100g

  • 523.0CNY

  • Detail

13453-69-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name LITHIUM METABORATE

1.2 Other means of identification

Product number -
Other names lithium,oxido(oxo)borane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13453-69-5 SDS

13453-69-5Synthetic route

Li(1+)*{(C6H5)B(OH)3}(1-)=Li{(C6H5)B(OH)3}

Li(1+)*{(C6H5)B(OH)3}(1-)=Li{(C6H5)B(OH)3}

A

lithium metaborate
13453-69-5

lithium metaborate

B

water
7732-18-5

water

C

benzene
71-43-2

benzene

Conditions
ConditionsYield
thermal decompn. in air at 115°C and in N2 atmosphere at 120°C;
Lithium-hydroxy-{2-(hydroxymethyl)-2-methyl-1,3-propandiolato(3-)-O,O'O''}-borat(1-) * 1.5H2O

Lithium-hydroxy-{2-(hydroxymethyl)-2-methyl-1,3-propandiolato(3-)-O,O'O''}-borat(1-) * 1.5H2O

A

lithium metaborate
13453-69-5

lithium metaborate

B

water
7732-18-5

water

Conditions
ConditionsYield
With oxygen byproducts: CO2; oxisative decompn. on heating;
With O2 byproducts: CO2; oxisative decompn. on heating;
cobalt lithium orthoborate

cobalt lithium orthoborate

A

cobalt(II,III) oxide

cobalt(II,III) oxide

B

lithium metaborate
13453-69-5

lithium metaborate

Conditions
ConditionsYield
In neat (no solvent, solid phase) heating in air (800°C);
lithium borohydride

lithium borohydride

water
7732-18-5

water

A

lithium metaborate
13453-69-5

lithium metaborate

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With cobalt(II) chloride at 20℃;
selenium
7782-49-2

selenium

lithium borohydride

lithium borohydride

lithium hydroxide
1310-65-2

lithium hydroxide

A

lithium metaborate
13453-69-5

lithium metaborate

B

dilithium diselenide

dilithium diselenide

Conditions
ConditionsYield
In water at 20℃; for 1h; Schlenk technique; Inert atmosphere; Sonication;
methanol
67-56-1

methanol

lithium metaborate
13453-69-5

lithium metaborate

A

water
7732-18-5

water

B

lithium tetramethanolatoborate
6867-35-2

lithium tetramethanolatoborate

Conditions
ConditionsYield
In methanol with exclusion of air in excess anhydrous methanol; between room temp. and boiling; by refluxing;
In methanol with exclusion of air in excess anhydrous methanol; between room temp. and boiling; by refluxing;
lithium metaborate
13453-69-5

lithium metaborate

mannitol
69-65-8

mannitol

Li(1+)*BO2(1-)*2C6H14O6*2H2O=LiBO2*2C6H14O6*2H2O

Li(1+)*BO2(1-)*2C6H14O6*2H2O=LiBO2*2C6H14O6*2H2O

Conditions
ConditionsYield
In water in concd.soln.; pptd. with alcohol;
In water in concd.soln.; pptd. with alcohol;
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

lithium metaborate
13453-69-5

lithium metaborate

water
7732-18-5

water

Lithium-hydroxy-{2-(hydroxymethyl)-2-methyl-1,3-propandiolato(3-)-O,O'O''}-borat(1-) * 1.5H2O

Lithium-hydroxy-{2-(hydroxymethyl)-2-methyl-1,3-propandiolato(3-)-O,O'O''}-borat(1-) * 1.5H2O

methanol
67-56-1

methanol

lithium metaborate
13453-69-5

lithium metaborate

Li-tetrakis(methoxy)borate *2CH3OH

Li-tetrakis(methoxy)borate *2CH3OH

Conditions
ConditionsYield
with anhydrous CH3OH; reflux; exclusion of air; addn. of dimethyl ether to filtrate; drying at room temp.;
with anhydrous CH3OH; reflux; exclusion of air; addn. of dimethyl ether to filtrate; drying at room temp.;
lithium metaborate
13453-69-5

lithium metaborate

calcium borate

calcium borate

beryllium oxide

beryllium oxide

beryllium calcium diborate

beryllium calcium diborate

Conditions
ConditionsYield
In neat (no solvent) melting, cooling from 1198 K to 698 K (6 K/h); washing (hot distd. water);
strontium(II) oxide

strontium(II) oxide

boron trioxide

boron trioxide

indium(III) oxide

indium(III) oxide

lithium metaborate
13453-69-5

lithium metaborate

strontium lithium indium pyroborate

strontium lithium indium pyroborate

Conditions
ConditionsYield
In neat (no solvent) melting SrO, In2O3, LiBO2 and B2O3 in Pt-crucible at 1303 K, cooling slow to 1003 K (10 K/h), cooling to 300 K (88 K/h); washing (hot distd. water);
boron trioxide

boron trioxide

lithium metaborate
13453-69-5

lithium metaborate

lithium catena-poly{3,4-dihydroxypentaborate-1:5-μ-oxo}

lithium catena-poly{3,4-dihydroxypentaborate-1:5-μ-oxo}

Conditions
ConditionsYield
In formic acid aq. formic acid; 573 K, 10 MPa, 8 d;
dysprosium((III) oxide

dysprosium((III) oxide

lithium metaborate
13453-69-5

lithium metaborate

boric acid
11113-50-1

boric acid

LiDy6O5(9+)*3BO3(3-)=LiDy6O5(BO3)3

LiDy6O5(9+)*3BO3(3-)=LiDy6O5(BO3)3

Conditions
ConditionsYield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
erbium(III) oxide

erbium(III) oxide

lithium metaborate
13453-69-5

lithium metaborate

boric acid
11113-50-1

boric acid

LiEr6O5(9+)*3BO3(3-)=LiEr6O5(BO3)3

LiEr6O5(9+)*3BO3(3-)=LiEr6O5(BO3)3

Conditions
ConditionsYield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
lithium metaborate
13453-69-5

lithium metaborate

europium(III) oxide

europium(III) oxide

boric acid
11113-50-1

boric acid

LiEu6O5(9+)*3BO3(3-)=LiEu6O5(BO3)3

LiEu6O5(9+)*3BO3(3-)=LiEu6O5(BO3)3

Conditions
ConditionsYield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
gadolinium(III) oxide

gadolinium(III) oxide

lithium metaborate
13453-69-5

lithium metaborate

boric acid
11113-50-1

boric acid

LiGd6O5(9+)*3BO3(3-)=LiGd6O5(BO3)3

LiGd6O5(9+)*3BO3(3-)=LiGd6O5(BO3)3

Conditions
ConditionsYield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
holmium(III) oxide

holmium(III) oxide

lithium metaborate
13453-69-5

lithium metaborate

boric acid
11113-50-1

boric acid

LiHo6O5(9+)*3BO3(3-)=LiHo6O5(BO3)3

LiHo6O5(9+)*3BO3(3-)=LiHo6O5(BO3)3

Conditions
ConditionsYield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
neodymium(III) oxide

neodymium(III) oxide

lithium metaborate
13453-69-5

lithium metaborate

boric acid
11113-50-1

boric acid

LiNd6O5(9+)*3BO3(3-)=LiNd6O5(BO3)3

LiNd6O5(9+)*3BO3(3-)=LiNd6O5(BO3)3

Conditions
ConditionsYield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
samarium(III) oxide

samarium(III) oxide

lithium metaborate
13453-69-5

lithium metaborate

boric acid
11113-50-1

boric acid

LiSm6O5(9+)*3BO3(3-)=LiSm6O5(BO3)3

LiSm6O5(9+)*3BO3(3-)=LiSm6O5(BO3)3

Conditions
ConditionsYield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
lithium metaborate
13453-69-5

lithium metaborate

thulia

thulia

boric acid
11113-50-1

boric acid

LiTm6O5(9+)*3BO3(3-)=LiTm6O5(BO3)3

LiTm6O5(9+)*3BO3(3-)=LiTm6O5(BO3)3

Conditions
ConditionsYield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
lithium metaborate
13453-69-5

lithium metaborate

terbium(III) oxide

terbium(III) oxide

boric acid
11113-50-1

boric acid

LiTb6O5(9+)*3BO3(3-)=LiTb6O5(BO3)3

LiTb6O5(9+)*3BO3(3-)=LiTb6O5(BO3)3

Conditions
ConditionsYield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
yttrium(III) oxide

yttrium(III) oxide

lithium metaborate
13453-69-5

lithium metaborate

boric acid
11113-50-1

boric acid

LiY6O5(9+)*3BO3(3-)=LiY6O5(BO3)3

LiY6O5(9+)*3BO3(3-)=LiY6O5(BO3)3

Conditions
ConditionsYield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
praseodymium(III) oxide

praseodymium(III) oxide

lithium metaborate
13453-69-5

lithium metaborate

boric acid
11113-50-1

boric acid

LiPr6O5(9+)*3BO3(3-)=LiPr6O5(BO3)3

LiPr6O5(9+)*3BO3(3-)=LiPr6O5(BO3)3

Conditions
ConditionsYield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
niobium(V) oxide

niobium(V) oxide

lithium metaborate
13453-69-5

lithium metaborate

(LiBO2)0.90(Nb2O5)010

(LiBO2)0.90(Nb2O5)010

Conditions
ConditionsYield
In melt calcd. amts. of compd. mixed, melted in covered Pt crucible, temp. raised to 1373 K (5 K/min) and maintained at this temp. for 1 h; melt poured onto preheated (400 K) stainless steel plate, quickly pressed by another plate, heated at 573 K for 6 h (heating and cooling rates 50 K/h);
niobium(V) oxide

niobium(V) oxide

lithium metaborate
13453-69-5

lithium metaborate

(LiBO2)0.80(Nb2O5)020

(LiBO2)0.80(Nb2O5)020

Conditions
ConditionsYield
In melt calcd. amts. of compd. mixed, melted in covered Pt crucible, temp. raised to 1373 K (5 K/min) and maintained at this temp. for 1 h; melt poured onto preheated (400 K) stainless steel plate, quickly pressed by another plate, heated at 573 K for 6 h (heating and cooling rates 50 K/h);
niobium(V) oxide

niobium(V) oxide

lithium metaborate
13453-69-5

lithium metaborate

(LiBO2)0.95(Nb2O5)005

(LiBO2)0.95(Nb2O5)005

Conditions
ConditionsYield
In melt calcd. amts. of compd. mixed, melted in covered Pt crucible, temp. raised to 1373 K (5 K/min) and maintained at this temp. for 1 h; melt poured onto preheated (400 K) stainless steel plate, quickly pressed by another plate, heated at 573 K for 6 h (heating and cooling rates 50 K/h);
niobium(V) oxide

niobium(V) oxide

lithium metaborate
13453-69-5

lithium metaborate

(LiBO2)0.85(Nb2O5)015

(LiBO2)0.85(Nb2O5)015

Conditions
ConditionsYield
In melt calcd. amts. of compd. mixed, melted in covered Pt crucible, temp. raised to 1373 K (5 K/min) and maintained at this temp. for 1 h; melt poured onto preheated (400 K) stainless steel plate, quickly pressed by another plate, heated at 573 K for 6 h (heating and cooling rates 50 K/h);
lithium metaborate
13453-69-5

lithium metaborate

water
7732-18-5

water

lithium metaborate dihydrate

lithium metaborate dihydrate

Conditions
ConditionsYield
at 90℃;

13453-69-5Related news

Determination of 24 trace elements in felsic rocks by inductively coupled plasma mass spectrometry after Lithium metaborate (cas 13453-69-5) fusion08/06/2019

An improved lithium metaborate fusion technique for inductively coupled plasma mass spectrometric analysis of felsic rocks is proposed. The method involves the dissolution of fused sample material with HF followed by treatment with HNO3. The decomposition method developed was used for the determ...detailed

Preparation of PIXE samples by Lithium metaborate (cas 13453-69-5) fusion08/05/2019

Materials containing a significant silicate matrix are often considered for element analysis by the PIXE method. In some circumstances such materials may not be conveniently prepared for sample analysis. It has been found that a lithium metaborate fusion-acid dissolution procedure works well for...detailed

Thermal dehydration of Lithium metaborate (cas 13453-69-5) dihydrate and phase transitions of anhydrous product08/04/2019

Reaction steps and mechanisms of the thermal dehydration of lithium metaborate dihydrate were investigated by means of thermoanalytical measurements, high temperature powder X-ray diffractometry, FT-IR spectroscopy, and microscopic observations. The first half of thermal dehydration was characte...detailed

13453-69-5Relevant articles and documents

Ultrasound-assisted synthesis of alkali metals diselenides (M2Se2) and their application for the gram-scale preparation of 2,2’-diselenobis(benzoic acid)

Krasowska, Dorota,Begini, Francesca,Santi, Claudio,Mangiavacchi, Francesca,Drabowicz, Jozef,Sancineto, Luca

, p. 24 - 37 (2019)

A simple and efficient method to convert elemental selenium into alkali metal diselenide was developed. The use of selenium and metal borohydride in a molar ratio of 1 to 0.125 in the presence of base, under “on water” conditions and ultrasound activation permitted the reduction of Se into Se22- to be completed within minutes. Thus obtained metal diselenide aqueous solution was then used in the multigram scale synthesis of 2,2’-diselenobis(benzoic acid) (DSBA) a valuable building block for the development of diverse and pivotal selenorganic compounds.

Synthesis, structural and vibrational analysis of LiMBO3 orthoborates (M = Mg, Co, Zn)

Belkebir,Tarte,Rulmont,Gilbert

, p. 311 - 316 (2008/10/08)

The structure of LiZnBO3 obtained by low temperature hydrothermal reaction has been determined previously in single crystals. We calculated the crystallographic cell of the phases obtained by solid-state reaction without melting by indexing their X-ray powder diffraction patterns. We found evidence that the structure of LiZnBO3 depends on the preparation method. The two structures found are monoclinic probably with the same Li-Zn cationic disorder, as evidenced by vibrational behavior. The cell parameters for the phase prepared at high temperature are a=7.9286(6), b=5.0934(3), c=6.1464(5) A, β = 104.3(5)°, Z=4. The magnesium and cobalt compounds are isomorphous and form a total solid solution. Their monoclinic cells is not related to the cells of the zinc derivative. The parameters of the unit cell are a=9.9155(8), b=8.8847(11), c=5.1577(4) A, β =9 1.231(8)°, Z=8 for the magnesium compound and a=10.1100(7), b=8.8518(8), c=5.1311(6) A, β = 91.358(7)°, Z=8 for the cobalt compound. The lithium cobalt borate is not very thermally stable and it is best synthesized by a two-step procedure. The effect of the lithium isotopic substitution on the vibrational frequencies shows that this cation is in tetrahedral coordination in all the phases. CNRS-Gauthier-Villars.

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