Welcome to LookChem.com Sign In|Join Free

CAS

  • or
(±)-(3-fluoro-3-methylpentyl)benzene is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

1347047-86-2 Suppliers

Post Buying Request

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier
  • 1347047-86-2 Structure
  • Basic information

    1. Product Name: (±)-(3-fluoro-3-methylpentyl)benzene
    2. Synonyms: (±)-(3-fluoro-3-methylpentyl)benzene
    3. CAS NO:1347047-86-2
    4. Molecular Formula:
    5. Molecular Weight: 180.265
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1347047-86-2.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (±)-(3-fluoro-3-methylpentyl)benzene(CAS DataBase Reference)
    10. NIST Chemistry Reference: (±)-(3-fluoro-3-methylpentyl)benzene(1347047-86-2)
    11. EPA Substance Registry System: (±)-(3-fluoro-3-methylpentyl)benzene(1347047-86-2)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1347047-86-2(Hazardous Substances Data)

1347047-86-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1347047-86-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,4,7,0,4 and 7 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1347047-86:
(9*1)+(8*3)+(7*4)+(6*7)+(5*0)+(4*4)+(3*7)+(2*8)+(1*6)=162
162 % 10 = 2
So 1347047-86-2 is a valid CAS Registry Number.

1347047-86-2Downstream Products

1347047-86-2Relevant articles and documents

Open-Shell Fluorination of Alkyl Bromides: Unexpected Selectivity in a Silyl Radical-Mediated Chain Process

Lovett, Gabrielle H.,Chen, Shuming,Xue, Xiao-Song,Houk,MacMillan, David W. C.

, p. 20031 - 20036 (2019)

We disclose a novel radical strategy for the fluorination of alkyl bromides via the merger of silyl radical-mediated halogen-atom abstraction and benzophenone photosensitization. Selectivity for halogen-atom abstraction from alkyl bromides is observed in the presence of an electrophilic fluorinating reagent containing a weak N-F bond despite the predicted favorability for Si-F bond formation. To probe this surprising selectivity, preliminary mechanistic and computational studies were conducted, revealing that a radical chain mechanism is operative in which kinetic selectivity for Si-Br abstraction dominates due to a combination of polar effects and halogen-atom polarizability in the transition state. This transition-metal-free fluorination protocol tolerates a broad range of functional groups, including alcohols, ketones, and aldehydes, which demonstrates the complementary nature of this strategy to existing fluorination technologies. This system has been extended to the generation of gem-difluorinated motifs which are commonly found in medicinal agents and agrochemicals.

Dehydroxylative Fluorination of Tertiary Alcohols

Zhang, Wei,Gu, Yu-Cheng,Lin, Jin-Hong,Xiao, Ji-Chang

supporting information, p. 6642 - 6646 (2020/09/02)

A large number of fluorination methods have been developed, but the construction of a tertiary C-F bond remains challenging. Herein, we describe an efficient dehydroxylative fluorination of tertiary alcohols with Selectfluor via the activation of a hydroxyl group by a Ph2PCH2CH2PPh2/ICH2CH2I system. Although the reagents appear to be not compatible (Selectfluor with the phosphine and I- generated in situ), the reactions occur rapidly to give the desired products in moderate to high yields. This work may present a new discovery in fluorination of alcohols since the reported methods are mainly limited to primary and secondary alcohols.

Synthesis of enantioenriched alkylfluorides by the fluorination of boronate complexes

Sandford, Christopher,Rasappan, Ramesh,Aggarwal, Varinder K.

, p. 10100 - 10103 (2015/09/01)

The enantiospecific conversion of chiral secondary boronic esters into alkylfluorides is reported. Boronate complexes derived from boronic esters and PhLi were used as nucleophiles, with Selectfluor II as the electrophilic fluorinating agent, to afford alkylfluorides in short reaction times. The addition of styrene as a radical trap was found to enhance enantiospecificity. A broad range of alkyl boronic esters were converted into alkylfluorides with almost complete enantiospecificity by this method.

Iridium-catalyzed allylic fluorination of trichloroacetimidates

Topczewski, Joseph J.,Tewson, Timothy J.,Nguyen, Hien M.

supporting information; experimental part, p. 19318 - 19321 (2012/01/06)

A rapid allylic fluorination method utilizing trichloroacetimidates in conjunction with an iridium catalyst has been developed. The reaction is conducted at room temperature under ambient air and relies on Et 3N?3HF reagent to provide branched allylic fluorides with complete regioselectivity. This high-yielding reaction can be conducted on a multigram scale and shows considerable functional group tolerance. The use of [18F]KF?Kryptofix allowed 18F- incorporation in 10 min.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 1347047-86-2