135761-35-2

Basic information

• Product Name: Benzenamine, 4-(trimethylsilyl)-N,N-bis[4-(trimethylsilyl)phenyl]-
• CAS NO: 135761-35-2
• Molecular Formula: C27H39NSi3
• Molecular Weight: 461.87
• Mol File: 135761-35-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-(trimethylsilyl)-N,N-bis[4-(trimethylsilyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-(trimethylsilyl)-N,N-bis[4-(trimethylsilyl)phenyl]-(135761-35-2)
• EPA Substance Registry System: Benzenamine, 4-(trimethylsilyl)-N,N-bis[4-(trimethylsilyl)phenyl]-(135761-35-2)

Safety Data

• Hazardous Substances Data: 135761-35-2(Hazardous Substances Data)

Upstream product

• 6999-03-7 1-bromo-4-(trimethylsilyl)benzene 
• 4316-58-9 tri(p-bromophenyl)amine 
• 75-77-4 chloro-trimethyl-silane 

Relevant articles and documents

Method for synthesizing organic aromatic nitrogen-containing compound by taking nitrogen as nitrogen source

The invention provides a method for synthesizing an organic aromatic nitrogen-containing compound by taking nitrogen as a nitrogen source, and belongs to the field of organic synthesis. The invention provides a method for synthesizing an organic aromatic nitrogen-containing compound by taking nitrogen as a nitrogen source, which is characterized by comprising the following steps of: 1, reducing nitrogen by lithium powder to form lithium nitride; and 2, reacting the lithium nitride with a halogenated aromatic compound under the action of a transition metal catalyst, a ligand, alkali and a phase transfer catalyst to obtain an organic aromatic nitrogen-containing compound; wherein the two steps of reactions are completed in one pot. The method realizes the conversion of cheap nitrogen to the high-added-value aromatic nitrogen-containing compound, and also has the advantages of mild reaction conditions, good compatibility of substrate functional groups, high yield and the like.

Substituted Triarylamine Cation-Radical Redox Systems - Synthesis, Electrochemical and Spectroscopic Properties, Hammet Behavior, and Suitability as Redox Catalysts

21 triarylamines (1n - 1z, 1za, 1zb) and triarylamine analogs (2a, 2b, 3a, 3b, 4a, 4b) with substituents in at least all three p positions and some of their cation-radical hexachloroantimonates have been synthesized.The electrochemical behavior has been studied by cyclic voltammetry.Most of the compounds show chemically and electrochemically reversible first oxidation waves in the formation of the cation radicals.With the exception of 4a and 4b, the second wave for the formation of the dication is chemically irreversible.The UV spectra of the triarylamine cation radicals have been obtained in the presence of a slight excess of SbCl5.A good Hammett correlation between the first anodic potential of only p-substituted triarylamines and the ?/?+ values has been established.Some redox-catalytic properties of triarylamine cation radicals are described. Key Words: Triarylamines / Cation radicals / Electrochemistry / Redox catalysts / Voltammetry, cyclic