13604-44-9

Basic information

• Product Name: 4-13-00-01311 (Beilstein Handbook Reference)
• CAS NO: 13604-44-9
• Molecular Formula: C₁₆H₂₀N₂S
• Molecular Weight: 272.414
• Mol File: 13604-44-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-13-00-01311 (Beilstein Handbook Reference)(CAS DataBase Reference)
• NIST Chemistry Reference: 4-13-00-01311 (Beilstein Handbook Reference)(13604-44-9)
• EPA Substance Registry System: 4-13-00-01311 (Beilstein Handbook Reference)(13604-44-9)

Safety Data

• Hazardous Substances Data: 13604-44-9(Hazardous Substances Data)

Upstream product

• 594-42-3 chlorothio-trichloro-methane 
• 121-69-7 N,N-dimethyl-aniline 
• 698-69-1 4-chloro-N,N-dimethylaniline 
• 155816-23-2 disulfur dithiocyanate 
• 64-17-5 ethanol 
• 15156-67-9 bis-(4-dimethylamino-phenyl)-sulfoxide 
• 75-15-0 carbon disulfide 
• 5397-29-5 4-(N,N-dimethylamino)phenyl disulfide 
• 7664-41-7 ammonia 
• 25661-63-6 sodium 4-N,N-dimethylaminobenzenethiolate 
• 603-35-0 triphenylphosphine 
• 71-43-2 benzene 
• 62-53-3 aniline 
• 222851-56-1 N-phenylsulfinylamine 

Downstream Products

• 68223-66-5 N,N-dimethyl-4-tritylmercapto-aniline 
• 121-69-7 N,N-dimethyl-aniline 
• 62849-42-7 bis-(4-dimethylamino-phenyl)-ether 

Relevant articles and documents

Copper-Catalyzed Double Thiolation to Access Sulfur-Bridged Imidazopyridines with Isothiocyanate

A copper(I)-catalyzed sulfur-bridged dimerization of imidazopyridines has been developed using isothiocyanate as the sulfur source. This method enables a switchable synthesis of bis(imidazo[1,2-a]pyridin-3-yl)sulfanes or bis(2-(imidazo[1,2-a]pyridin-2-yl)phenyl)sulfanes in the presence of 4-dimethylaminopyridine (DMAP) or K2CO3 when different imidazopyridines were employed. Under optimized conditions, a variety of sulfur-bridged imidazopyridines were obtained in good yields. Moreover, thiourea was proved to be the key intermediate under catalytic system A.

Utilisations synthetiques d'une electrode soluble au soufre. IV. Creation de l'enchainement C-S-C a partir d'hydrocarbures aromatiques, d'heterocycles et d'amines aromatiques

Use of a sacrificial sulfur electrode in electroorganic chemistry.IV.Formation of the C-S-C bond from aromatic hydrocarbons, heterocycles and aromatic amines.The electrophile S2+ was prepared in organic media by oxidation of a carbon-sulfur electrode.This species can react with aromatic hydrocarbons, heterocycles and aromatic amines to produce organic monosulfides. carbon-sulfur electrode / sacrificial electrode / sulfur cation / organic sulfide / electrophilic substitution

SULPHURATION OF ELECTRON-RICH ARENES WITH SULPHENAMIDES AND AMINOSULPHENYL CHLORIDES

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