13883-39-1Relevant articles and documents
Divergent synthesis of carbosilane wedges as dendritic building blocks: A new strategy towards core functionalised carbosilane dendrimers
Van Heerbeek, Rieko,Reek, Joost N.H.,Kamer, Paul C.J.,Van Leeuwen, Piet W.N.M.
, p. 7127 - 7130 (1999)
A divergent route for the synthesis of carbosilane wedges containing either a bromine or amine as a focal point has been developed for the construction of core functionalised dendrimers; carbosilane dendrimers up to the third generation containing a 1,3,5-benzene triamide core capable of binding guest molecules via hydrogen bonding have been prepared.
Packing for use in resolution
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, (2008/06/13)
The packing for use in resolution proposed for the liquid chromatography for particularly the opti-cal resolution of racemic compounds is prepared by reacting a silica gel carrier with a so-called silane treating agent to introduce a spacer part therein and chemically bonding it with a copper salt of a carboxylic or thiocarboxylic acid selected from the group consisting of optically active D- and L-2--acetizinecaroxylic acid, proline, hydroxyproline and allohydroxyproline. The steric bulkiness, the distance between the silica gel and the optically active group and the degree of hydrophobicity are specified so as to obtain an excellent resolving power.
SILAETHENE I. DARSTELLUNG UND CHARAKTERISIERUNG VON MONOSILACYCLOBUTANEN
Auner, N.,Grobe, J.
, p. 25 - 52 (2007/10/02)
Monosilacyclobutanes of the type RR' are prepared by ring closure reactions of 3-halopropylhalosilanes and by substitution of SiCl containing silacyclobutane rings with organometallic reagents (RMgX, LiR, NaCp).Under optimal experimental conditions yields between 50 and 95percent can be obtained by both procedures.Characterization of the compounds is accomplished by analytical (C, H, N) and NMR, IR and mass spectroscopic investigations.