13902-07-3

Basic information

• Product Name: eudesm-4-en-11-ol
• CAS NO: 13902-07-3
• Molecular Weight: 222.371
• Mol File: 13902-07-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: eudesm-4-en-11-ol(CAS DataBase Reference)
• NIST Chemistry Reference: eudesm-4-en-11-ol(13902-07-3)
• EPA Substance Registry System: eudesm-4-en-11-ol(13902-07-3)

Safety Data

• Hazardous Substances Data: 13902-07-3(Hazardous Substances Data)

Upstream product

• 263860-43-1 11,12-Oxido-α-cyperone 
• 133056-10-7 eudeshonokiol B 
• 126654-55-5 eudeshonokiol A 
• 88494-79-5 1-hydroxy γ-eudesmol 
• 186376-50-1 hinesol 
• 1460-74-8 1α,10α-epoxyhines-11-ol 
• 157192-94-4 <2S-(2RS,6RS,9SR)>-9-<1-(triethylsilyl)oxy-1-methylethyl>-2,6-dimethyl-1,5-cyclodecanedione 
• 157192-96-6 <4S-(4α,4aα,6α,8aα)>-octahydro-4,8a-dimethyl-6-<1-(triethylsilyl)oxy-1-methylethyl>-1(2H)-naphthalenone 
• 157192-99-9 <6R-(6α,8aα)>-2,3,5,6,7,8,8a-hexahydro-4,8a-dimethyl-6-<1-(triethylsilyl)oxy-1-methylethyl>-1(2H)-naphthalenone 
• 67697-24-9 <2S-(2RS,6RS,9SR)>-9-(1-hydroxy-1-methylethyl)-2,6-dimethyl-1,5-cyclodecanedione 
• 489-86-1 guaiol 
• 473-08-5 eudesma-4,11-dien-3-one 
• 157241-50-4 (+)-hedycaryol 
• 88494-80-8 (6R,8aR)-6-(1-Hydroxy-1-methyl-ethyl)-4,8a-dimethyl-3,5,6,7,8,8a-hexahydro-2H-naphthalen-1-one 

Downstream Products

• 119765-86-5 11-hydroxy-4,5-seco-endesmane-4,5-dione 

Relevant articles and documents

First enantioselective total syntheses and absolute configurations of 4,5-dioxo-seco-γ-eudesmol and 5β,11-dihydroxyiphionan-4-one, two aglycones of naturally occurring sesquiterpenes with new skeletons

A facile synthetic route to two new carbon skeleton sesquiterpenes 4,5-dioxo-seco-γ-eudesmol and 5β,11-dihydroxyiphionan-4-one from (+)-dihydrocarvone has been described. The configuration of the 5β,11-dihydroxyipbionan-4-one was confirmed by stereospecific synthesis.

Biotransformation of (+/-)-4,8-dimethylcyclodeca-3(E),7(E)-dien-1β-ol and (+)-Hedycaryol by Cichorium intybus

The biotransformation of the synthetic (E,E)-1,5-cyclodecadienol 5 and (+)-hedycaryol (11) by a root suspension of fresh chicory has been investigated.Incubation of 5 with a root suspension gave a 2:1 mixture of epimeric eudesmanediols 7a and 7b whereas 11 was selectively converted into cryptomeridiol (12).An explanation for the obtained results is proposed.

NEUROTROPHIC SESQUITERPENE-NEOLIGNANS FROM MAGNOLIA OBOVATA: STRUCTURE AND NEUROTROPHIC ACTIVITY

Novel sesquiterpene-neolignans, eudesobovatols A (1) and B (2), eudesmagnolol (3), eudeshonokiols A (4) and B (5), clovanemagnolol (6), and caryolanemagnolol (7), have been isolated from the bark of Magnolia obovata.Their structures were elucidated to be sesquiterpenes (eudesmol, 4,4,8-trimethyltricyclo2,5>dodecane-1,9-diol, and clovanediol) combined through ether bond with neolignans such as obovatol, honokiol, and magnolol on the basis of spectral data, degradation, and/or synthesis.Compounds 1, 6, and 7 were found to exhibit interesting neurotrophic activity on a neuronal cell culture system derived from fetal rat hemisphere.