14143-01-2

Basic information

• Product Name: diethyl 3-methylphenyl phosphate
• Synonyms: Diethyl 3-methylphenyl phosphate; Phosphoric acid, diethyl 3-methylphenyl ester
• CAS NO: 14143-01-2
• Molecular Formula: C₁₁H₁₇O₄P
• Molecular Weight: 244.224
• Mol File: 14143-01-2.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 288.2°C at 760 mmHg
• Flash Point: 142°C
• Density: 1.13g/cm³
• Vapor Pressure: 0.00412mmHg at 25°C
• Refractive Index: 1.485
• CAS DataBase Reference: diethyl 3-methylphenyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 3-methylphenyl phosphate(14143-01-2)
• EPA Substance Registry System: diethyl 3-methylphenyl phosphate(14143-01-2)

Safety Data

• Hazardous Substances Data: 14143-01-2(Hazardous Substances Data)

Upstream product

• 32578-31-7 3-tolyl triflate 
• 54058-00-3 diethyl phosphite potassium salt 
• 78-40-0 triethyl phosphate 
• 108-39-4 3-methyl-phenol 
• 762-04-9 phosphonic acid diethyl ester 
• 814-49-3 diethyl chlorophosphate 
• 125320-80-1 Dicyclohexyl-amine; compound with 3-methyl-phenol 

Downstream Products

• 253342-48-2 4,4,5,5-tetramethyl-2-m-tolyl-1,3,2-dioxaborolane 
• 17171-17-4 4'-methoxy-3-methylbiphenyl 
• 129529-19-7 2-(Diethyl-phosphinoyl)-5-methyl-phenol 
• 80615-39-0 (2-Hydroxy-4-methyl-phenyl)-phosphonic acid diethyl ester 
• 7025-91-4 4-m-tolylmorpholine 

Relevant articles and documents

Electrochemical phosphorylation of arenols and anilines leading to organophosphates and phosphoramidates

A practical phosphorylation for generating organophosphates and phosphoramidatesviaelectrochemical dehydrogenative cross-coupling of P(O)H compounds with arenols and anilines is disclosed. This method involves using inorganic iodide salts as both redox catalysts and electrolytes in an undivided cell without the addition of oxidants or bases. A preliminary mechanistic study suggests that radicals are not involved in this process. This method is green and eco-friendly and has good functional group tolerance, high yields and broad substrate scope, with the potential for practical synthesis.

Tf2O-Promoted Activating Strategy of Phosphate Analogues: Synthesis of Mixed Phosphates and Phosphinate

A metal-, toxic chloride reagent-free activating strategy of various phosphates has been developed. This method enables the facile synthesis of functional phosphates such as alkyl phosphates, aza phosphates, thiophosphate, and mixed diaryl phosphates. A transient phosphorylpyridin-1-ium species in situ generated from phosphates with Tf2O/pyridine readily undergoes a substitution reaction with diverse nucleophiles to form versatile phosphate compounds.

Pd(II)-catalyzed ortho-arylation of aryl phosphates and aryl hydrogen phosphates with diaryliodonium triflates

Functionalized biaryl compounds were successfully synthesized using phosphates as the ortho-directing group in the Pd(II)/Pd(IV) catalytic cycle.