14239-51-1

Basic information

• Product Name: MERCURICDIETHYLDITHIOCARBAMATE
• Synonyms: MERCURICDIETHYLDITHIOCARBAMATE;Bis(diethyldithiocarbamic acid)mercury(II) salt
• CAS NO: 14239-51-1
• Molecular Formula: C₁₀H₂₀HgN₂S₄
• Molecular Weight: 497.15
• Mol File: 14239-51-1.mol
• Article Data: 2

Chemical Properties

• Melting Point: 128.5°C
• Boiling Point: 88.75°C
• Appearance: /solid
• CAS DataBase Reference: MERCURICDIETHYLDITHIOCARBAMATE(CAS DataBase Reference)
• NIST Chemistry Reference: MERCURICDIETHYLDITHIOCARBAMATE(14239-51-1)
• EPA Substance Registry System: MERCURICDIETHYLDITHIOCARBAMATE(14239-51-1)

Safety Data

• Hazardous Substances Data: 14239-51-1(Hazardous Substances Data)

Usage

Safety Profile

Poison by intravenous andintraperitoneal routes. When heated todecomposition it emits very toxic fumes of NOx, SOx, andHg.

InChI:InChI=1S/2C5H11NS2.Hg/c2*1-3-6(4-2)5(7)8;/h2*3-4H2,1-2H3,(H,7,8);/q;;+2/p-2

Upstream product

• 75-15-0 carbon disulfide 
• 109-89-7 diethylamine 
• 148-18-5 sodium N,N-diethyldithiocarbamate 
• 20393-93-5 {As((C₂H₅)2NCSS)3} 
• 14302-87-5 mercury ion 
• 1000068-52-9 tris(N,N-diethyldithiocarbamato)bismuth(III) 
• 13963-59-2 tris(N,N-diethyldithiocarbamato)iron(III) 
• 17549-30-3 bis(N,N-diethyldithiocarbamato)lead 
• 5601-08-1 Hg(ipxa)2 
• 125697-79-2 {Ph₃PCH₂Ph}{edtc} 
• 14267-17-5 nickel(II) diethyldithiocarbamate 
• 38351-46-1 silver diethyldithiocarbamate 
• 13681-87-3 bis(N,N-diethyldithiocarbamato)copper(II) 
• 15685-17-3 bis(diethyldithiocarbamate)manganese(II) 

Downstream Products

• 118085-39-5 Hg(S₂CN(CH₂CH₃)2)(P(C₆H₁₁)3)(ClO₄) 

Relevant articles and documents

Thermal characterization of mercury(II) bis(dialkyldithiocarbamate) complexes

The mercury(II) bis(dialkyldithiocarbamate) complexes, Hg(S 2CN-R2)2, in which R=ethyl, n-propyl, n-butyl and iso-butyl were characterized by TG, DSC, FTIR and elemental analysis. The TG curves presented two thermal decomposition stages; the first stage can be attributed to the partial decomposition of ligand and also to mercury sulfide decomposition. The second stage is representative for the decomposition of ligand fragments. The overlaid TG/DSC curves indicated that the decomposition of the complexes takes place the liquid phase. According to the isothermal kinetic data the phase-boundary controlled kinetic models describes the best the decomposition of complexes. The data obtained by the Ozawa method suggest the following stability order for the complexes: iBu>nPr>nBu>Et.