14309-25-2

Basic information

• Product Name: Trityl azide
• Synonyms: AZIDOTRIPHENYLMETHANE 95%;TRITYL AZIDE 95%;1,1',1''-(Azidomethylidyne)trisbenzene;AZIDOTRIPHENYLMETHANE;TIMTEC-BB SBB008024;TRIPHENYLMETHYL AZIDE;TRITYL AZIDE;1,1’,1’’-(azidomethylidyne)tris-benzen
• CAS NO: 14309-25-2
• Molecular Formula: C₁₉H₁₅N₃
• Molecular Weight: 285.34
• Mol File: 14309-25-2.mol
• Article Data: 26

Chemical Properties

• Melting Point: 61-62°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: Trityl azide(CAS DataBase Reference)
• NIST Chemistry Reference: Trityl azide(14309-25-2)
• EPA Substance Registry System: Trityl azide(14309-25-2)

Safety Data

• Statements: 2-11
• Safety Statements: 15-17-33
• RIDADR: 1325
• Hazardous Substances Data: 14309-25-2(Hazardous Substances Data)

Usage

Uses

Triphenylmethyl Azide is used in preparation of FSO2N3 as reagent for synthesis of Azide compounds from corresponding Amines.

InChI:InChI=1/C19H16N3/c20-22-21-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,20H/q+1

Upstream product

• 596-43-0 bromo-triphenyl-methane 
• 2913-53-3 9-deutero-9-phenylfluorene 
• 65-85-0 benzoic acid 
• 93-58-3 benzoic acid methyl ester 
• 1235-22-9 allyl trityl ether 
• 519-73-3 triphenylmethane 
• 18909-18-7 1-diphenylmethylene-4-trityl-2,5-cyclohexadiene 
• 3695-77-0 triphenylmethanethiol 
• 119-61-9 benzophenone 
• 100-58-3 phenylmagnesium bromide 
• 93-99-2 benzoic acid phenyl ester 
• 76-83-5 trityl chloride 
• 596-31-6 methoxytriphenylmethane 
• 5824-40-8 Triphenylmethylamin 

Downstream Products

• 28212-50-2 C₂₅H₂₁F₉NO₃P 
• 18909-18-7 1-diphenylmethylene-4-trityl-2,5-cyclohexadiene 
• 1447045-30-8 C₄₀H₄₆N₂P₂ 
• 1354564-59-2 [η5-1,2,4-(Me3C)3C5H2]2Th=NCPh3 
• 148234-76-8 1-trityl-1H-1,2,3-triazol-4-carbaldehyde 

Relevant articles and documents

Controlled synthesis of polyphosphazenes with chain-capping agents

N-alkyl phosphoranimines were synthesized via the Staudinger reaction of four different alkyl azides with tris(2,2,2-trifluoroethyl) phosphite. N-adamantyl, N-benzyl, N-t-butyl, and N-trityl phosphoranimines were thoroughly characterized and evaluated as

Molecular batteries based on carbon - Carbon bond formation and cleavage in titanium and vanadium Schiff base complexes

The reduction of titanium(III) and vanadium(III) salophen complexes led to the reductive coupling of imino groups in the ligands, and thus to the formation of C-C-bonded dimers which released electrons on subsequent cleavage of the C-C bond. On reduction

Facile Direct Coupling Reactions of MOM-protected Benzylic Alcohols Using Aluminum Chloride

MOM group is one of the most commonly used protecting groups for alcohols. This study describes novel direct functionalization of the MOM-protected benzylic alcohols. Preparation of allylic compounds from benzyl MOM ethers was successfully achieved by utilization of allyltrimethylsilane and AlCl3. In addition, direct azidation of benzyl MOM ethers using TMSN3 was successful carried out under AlCl3-mediated reaction conditions. These results demonstrate that this novel synthetic procedure is a promising approach to direct functionalization of MOM-protected alcohols including allylation and azidation.

Direct AlCl3-catalyzed transformation of benzyl THP ethers and allyl benzyl ethers

THP and allyl groups are frequently used for the protection of alcohols. In this study, novel direct transformations of benzyl THP ethers and allyl benzyl ethers, protected forms of alcohols, are reported. TMSN3 and AlCl3 were employ