1431320-56-7Relevant articles and documents
Molecular dynamics and ligand exchange in magnesium complexes: Evidence for both dissociative and associative ligand exchange
Chisholm, Malcolm H.,Choojun, Kittisak,Chow, Albert S.,Fraenkel, Gideon
, p. 3264 - 3266 (2013/04/24)
Making a swap: The titled studies provide substantial evidence for the kinetically labile Mg2+ ion reacting through both a dissociative (see scheme; thf=tetrahydrofuran) and an associative interchange mechanism. The findings are particularly relevant to the reactions involving [LMgnBu(thf)] and rac-lactide in ring-opening polymerization reactions.