144002-27-7

Basic information

• Product Name: allyl 6-O-(tert-butyldiphenylsilyl)-D-galactopyranosyl-β-(1,4)-2-acetamido-2-deoxy-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside
• Synonyms: allyl 6-O-(tert-butyldiphenylsilyl)-D-galactopyranosyl-β-(1,4)-2-acetamido-2-deoxy-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside
• CAS NO: 144002-27-7
• Molecular Weight: 900.226
• Mol File: 144002-27-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: allyl 6-O-(tert-butyldiphenylsilyl)-D-galactopyranosyl-β-(1,4)-2-acetamido-2-deoxy-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 6-O-(tert-butyldiphenylsilyl)-D-galactopyranosyl-β-(1,4)-2-acetamido-2-deoxy-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside(144002-27-7)
• EPA Substance Registry System: allyl 6-O-(tert-butyldiphenylsilyl)-D-galactopyranosyl-β-(1,4)-2-acetamido-2-deoxy-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside(144002-27-7)

Safety Data

• Hazardous Substances Data: 144002-27-7(Hazardous Substances Data)

Upstream product

• 54400-75-8 allyl 2-acetamido-2-deoxy-β-D-glucopyranoside 
• 7296-64-2 β-D-galactopyranoside 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 144002-25-5 -(2,3)-<6-O-(tert-butyldiphenylsilyl)-β-D-galactosyl>-(1,4)-allyl 2-acetamido-2-deoxy-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside 
• 147072-67-1 C₆₉H₉₂N₂O₂₃Si₂ 

Relevant articles and documents

Synthesis and use of glycosyl phosphites: An effective route to glycosyl phosphates, sugar nucleotides, and glycosides

An efficient and convenient synthetic route to glycosyl phosphites and phosphates has been developed that uses dibenzyl N,N-diethylphosphoramidite as a phosphitylating reagent. Glycosyl phosphites and phosphates of 2-acetamido-2-deoxy-D-galactose (GalNAc) (29), 2-acetamido-2-deoxy-D-glucose (GlcNAc) (30), D-galactose (Gal) (31), D-glucose (Glc) (32), D-mannose (Man) (33), L-rhamnose (Rha) (34), L-fucose (Fuc) (35), and N-acetylneuraminic acid (NeuAc) (41) were prepared by this procedure. Compounds 29 and 30 were obtained as α anomers exclusively, whereas compounds 31, 32, and 41 were obtained as β anomers, and compounds 33 and 34, as α anomers, predominately. The phosphates are useful for the synthesis of sugar nucleotides, and the phosphites are effective glycosylation reagents.