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14446-67-4

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14446-67-4 Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 54, p. 2726, 1989 DOI: 10.1021/jo00272a050Tetrahedron Letters, 29, p. 4949, 1988 DOI: 10.1016/S0040-4039(00)80649-8

Check Digit Verification of cas no

The CAS Registry Mumber 14446-67-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,4,4 and 6 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 14446-67:
(7*1)+(6*4)+(5*4)+(4*4)+(3*6)+(2*6)+(1*7)=104
104 % 10 = 4
So 14446-67-4 is a valid CAS Registry Number.
InChI:InChI=1/C8H15N/c1-2-6-9-7-4-3-5-8-9/h2H,1,3-8H2

14446-67-4 Well-known Company Product Price

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  • Alfa Aesar

  • (L12312)  1-Allylpiperidine, 97%   

  • 14446-67-4

  • 5g

  • 1107.0CNY

  • Detail

14446-67-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-prop-2-enylpiperidine

1.2 Other means of identification

Product number -
Other names prop-2-enylpiperidine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14446-67-4 SDS

14446-67-4Relevant articles and documents

Hydrosilylation of nitrogen-containing organic compounds: Model studies

Chechelska-Noworyta, Aleksandra,Owińska,Hasik, Magdalena

, (2019)

1,1,3,3-tetramethyldisiloxane (M2H) was used as the hydrosilylating agent for nitrogen-containing alkene derivatives: N-allylaniline (Naa), N-allylcyclohexylamine (Nach), N-allylpiperidine (Nap), 4-vinylpyridine (4VP) and 2-vinylpyri

Nucleophilic substitution reaction of α-siloxyamines with organometallics: A new method for α-substitution of tertiary amines via their N-oxides

Tokitoh,Okazaki

, p. 4677 - 4680 (1984)

-

Solvent interactions in the allylation of piperidine

Devender,Manikyamba

, p. 421 - 425 (2009)

The reaction between allylbromide and piperidine has been studied in different protic and aprotic solvents. The reaction is first order with respect to [allylbromide] and [piperidine]. A correlation analysis of the rate data with solvent properties shows that polarity (Y ), polarizability (P), and electrophilicity (E) of the solvent simultaneously influence the rate of reaction. From the regression analysis, information regarding the relative solvation of the reactants and the activated complex is obtained and a solvation model is proposed.

Photochemical Activation of Tertiary Amines for Applications in Studying Cell Physiology

Asad, Naeem,Deodato, Davide,Lan, Xin,Widegren, Magnus B.,Phillips, David Lee,Du, Lili,Dore, Timothy M.

supporting information, p. 12591 - 12600 (2017/09/23)

Representative tertiary amines were linked to the 8-cyano-7-hydroxyquinolinyl (CyHQ) photoremovable protecting group (PPG) to create photoactivatable forms suitable for use in studying cell physiology. The photoactivation of tamoxifen and 4-hydroxytamoxifen, which can be used to activate Cre recombinase and CRISPR-Cas9 gene editing, demonstrated that highly efficient release of bioactive molecules could be achieved through one- and two-photon excitation (1PE and 2PE). CyHQ-protected anilines underwent a photoaza-Claisen rearrangement instead of releasing amines. Time-resolved spectroscopic studies revealed that photorelease of the tertiary amines was extremely fast, occurring from a singlet excited state of CyHQ on the 70 ps time scale.

Tsuji-trost N-allylation with allylic acetates by using a cellulose-palladium catalyst

Vaddula, Buchi Reddy,Saha, Amit,Varma, Rajender S.,Leazer, John

supporting information, p. 6707 - 6709 (2013/01/15)

Allylic amines were synthesized by a simple procedure using a biodegradable and easily recyclable heterogeneous cellulose-Pd catalyst through N-allylation of primary and secondary amines. The scope of this protocol includes aliphatic and benzylamines with substituted and unsubstituted allyl acetates and culminates in high yield syntheses. The highlights of the protocol include a ligand-free reaction, simple workup, and catalyst recyclability. Allylic amines were synthesized by N-allylation of primary and secondary amines through a simple and easy procedure involving the use of a heterogeneous cellulose-Pd catalyst; aliphatic and benzylamines underwent facile reaction with substituted and unsubstituted allyl acetates in high yields. Copyright

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