14527-51-6

Basic information

• Product Name: 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE
• Synonyms: 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE;RARECHEM AS SA 0009;5 10 15 20-TETRA-P-TOLYL-21H 23H-PORPHI&;5,10,15,20-Tetra(4-methylphenyl)-21H,23H-porphine;meso-Tetra(4-methylphenyl)porphine;21H,23H-Porphine, 5,10,15,20-tetrakis(4-methylphenyl)-;Tetrakis(4-Methylphenyl)-porphine;5,10,15,20-Tetrakis(p-tolyl)porphyrin
• CAS NO: 14527-51-6
• Molecular Formula: C₄₈H₃₈N₄
• Molecular Weight: 670.84
• Mol File: 14527-51-6.mol

Chemical Properties

• Melting Point: >300℃
• Appearance: /
• Density: 1.207 g/cm³
• Refractive Index: 1.673
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE(14527-51-6)
• EPA Substance Registry System: 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE(14527-51-6)

Safety Data

• Hazardous Substances Data: 14527-51-6(Hazardous Substances Data)

Usage

Uses

Used in Research Applications:
5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE is used as a research compound for exploring its potential applications in various scientific fields. The compound's unique structure and properties make it an interesting subject for study, with possible implications in areas such as materials science, chemistry, and biology.
Used in Photodynamic Therapy (PDT) Research:
In the field of photodynamic therapy, 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE is used as a photosensitizer for investigating its potential in treating various types of cancer. The compound's ability to absorb light and generate reactive oxygen species (ROS) makes it a promising candidate for PDT, where it can potentially cause cell death in cancerous tissues upon light activation.
Used in Solar Energy Research:
5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE is also used in research related to solar energy, specifically in the development of dye-sensitized solar cells (DSSCs). The compound's light-harvesting properties and ability to transfer energy make it a candidate for improving the efficiency of these solar cells.
Used in Analytical Chemistry:
In analytical chemistry, 5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE is used as a selective and sensitive probe for the detection of various analytes, such as metal ions and small molecules. The compound's unique binding properties and optical characteristics make it a valuable tool for developing new analytical methods and sensors.
Used in Materials Science:
5,10,15,20-TETRA-P-TOLYL-21H,23H-PORPHINE is used in materials science research to explore its potential in creating novel materials with specific properties. The compound's structure and electronic properties make it a candidate for developing new materials with applications in areas such as electronics, optoelectronics, and sensors.

InChI:InChI=1/C48H38N4/c1-29-5-13-33(14-6-29)45-37-21-23-39(49-37)46(34-15-7-30(2)8-16-34)41-25-27-43(51-41)48(36-19-11-32(4)12-20-36)44-28-26-42(52-44)47(40-24-22-38(45)50-40)35-17-9-31(3)10-18-35/h5-28,49-50H,1-4H3/b45-37-,45-38-,46-39-,46-41-,47-40-,47-42-,48-43-,48-44-

Upstream product

• 104-87-0 4-methyl-benzaldehyde 
• 189638-16-2 2,2'-((3-nitrophenyl)methylene)bis(1H-pyrrole) 
• 122-85-0 para-acetamidobenzaldehyde 
• 147804-55-5 5-(4-methylphenyl)dipyrromethane 
• 109-97-7 pyrrole 
• 99-61-6 3-nitro-benzaldehyde 
• 19496-18-5 C₄₈H₃₆N₄^(2-)*Cl^(1-)*Fe⁽³⁺⁾ 
• 68-12-2 N,N-dimethyl-formamide 
• 552-89-6 2-nitro-benzaldehyde 
• 109088-80-4 2,5-bis[(4-tolyl)hydroxymethyl]thiophene 
• 1122-91-4 4-bromo-benzaldehyde 
• 116288-00-7 Propionic acid 4-[9-(4-formyl-phenyl)-[1,10]phenanthrolin-2-yl]-benzyl ester 
• 6363-86-6 2-formyl-9,10-anthraquinone 
• 606-20-2 2,6-dinitrotoluene 

Downstream Products

• 19414-67-6 5,10,15,20-tetrakis(4-methylphenyl)porphyrinatozinc(II) 
• 19414-65-4 meso-tetratolylporphyrinatocobalt(II) 
• 19496-18-5 5,10,15,20-tetrakis(4-methylphenyl)porphyrinatoiron(III) chloride 
• 205259-72-9 C₄₈H₃₆N₄Rh⁽¹⁺⁾*Cl^(1-) 
• 26334-83-8 dichloro[5,10,15,20-tetrakis(p-tolyl)porphinato]tin(IV) 

Relevant articles and documents

Design and synthesis of porphyrins bearing catechols

The synthesis of meso-tetraarylporphyrines bearing 1-4 catechoylamid groups was achieved. Among the four new compounds prepared, the structure of the disubstituted ligand was elucidated in the solid state by an X-ray analysis.

Cyclotriphosphazene ring as a platform for multiporphyrin assemblies

A simple method has been employed to synthesize a cyclotriphosphazene appended with six porphyrins. The reaction of one equivalent of hexachlorocyclotriphosphazene with six equivalents of 5-(4-hydroxyphenyl)-10,15, 20-tri(p-tolyl)porphyrin or -21-thiaporp

Unexpected one-pot synthesis of A3-type unsymmetrical porphyrin

The first direct synthesis of A3-type unsymmetrical porphyrin is achieved via conventional pyrrole-aldehyde condensation in a one-pot procedure in an appreciable yield. Generalization of this approach to a variety of other aldehydes revealed th

Solution Characterization of Copper(II) and Silver(II) Porphyrins and the One-Electron Oxidation Products by Nuclear Magnetic Resonance Spectroscopy

The Cu(II) and Ag(II) complexes of tetraphenylporphyrin, octaethylporphyrin, etioporphyrin I, and the one-electron oxidation products of these metalloporphyrin species have been examined by nuclear magnetic resonance (NMR) spectroscopy.Deuterium NMR spect

Tetraphenylporphyrin derivatives possessing piperidine group as potential agents for photodynamic therapy

Photodynamic therapy (PDT) is a noninvasive therapeutic and promising procedure in cancer treatment and has attracted considerable attention in recent years. In the present paper, 2-piperidinetetraphenylporphyrin derivatives (P1–P3) conjugated with differ

Thiaporphyrins with one, two and four unsubstituted meso-carbons: Synthesis and functionalization

Thiaporphyrins with one, two and four unsubstituted meso carbons were synthesized from easily available thiophene diols. The reactivity at these carbons was demonstrated by carrying out series of reactions and some very useful functional groups were introduced. ( Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

Novel fullerene receptors based on calixarene-porphyrin conjugates

Several different synthetic approaches enabling a direct covalent connection between the meso-position of porphyrin and the upper rim of calix[4]arene have been studied. The best results were obtained via condensation of an excess of pyrrole and p-methylb

Cobalt Porphyrin-Polypyridyl Surface Coatings for Photoelectrosynthetic Hydrogen Production

Hybrid materials that link light capture and conversion technologies with the ability to drive reductive chemical transformations are attractive as components in photoelectrosynthetic cells. We show that thin-film polypyridine surface coatings provide a molecular interface to assemble cobalt porphyrin catalysts for hydrogen evolution onto a visible-light-absorbing p-type gallium phosphide semiconductor. Spectroscopic techniques, including grazing angle attenuated total reflection Fourier transform infrared spectroscopy, confirm that the cobalt centers of the porphyrin macrocycles coordinate to pyridyl nitrogen sites of the organic surface coating. The cobalt porphyrin surface concentration and fraction of pyridyl sites coordinated to a cobalt center are quantified using complementary methods of ellipsometry, inductively coupled plasma mass spectrometry, and X-ray photoelectron spectroscopy. In aqueous solutions under simulated solar illumination the modified cathode is photochemically active for hydrogen production, generating the product gas with near-unity Faradaic efficiency at a rate of ≈10 μL min-1 cm-2 when studied in a three-electrode configuration and polarized at the equilibrium potential of the H+/H2 couple. This equates to a photoelectrochemical hydrogen evolution reaction activity of 17.6 H2 molecules s-1 Co-1, the highest value reported to date for a molecular-modified semiconductor. Key features of the functionalized photocathode include (1) the relative ease of synthetic preparation made possible by application of an organic surface coating that provides molecular recognition sites for immobilizing the cobalt porphyrin complexes at the semiconductor surface and (2) the use of visible light to drive cathodic fuel-forming reactions in aqueous solutions with no added organic acids or sacrificial chemical reductants.

FSM-16: Recyclable Mesoporous Acid Promoter for meso-Tetraarylporphyrin Synthesis

A new porous silicate, FSM-16 with a pore size of 2.8 nm in diameter is remarkably effective for meso-tetraarylporphyrin synthesis and can be used repeatedly without any efficiency loss after calcination at 500 deg C in air.

Structurally controlled porphyrin-aggregation process in phospholipid membranes

Structurally controlled aggregation course for five porphyrins (etioporphyrin [EP], 5-mono- and 5,15-di-[p-tolyl]etioporphyrin [TP and DTP], 5,10,15,20-tetrakis[p-tolyl]porphin [TTP], and 5,10,15,20-tetrakis[3,5-di-tert-butylphenyl]porphin [TBP]) in dipal