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1466-88-2

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1466-88-2 Usage

Chemical Properties

light yellow to yellow-brown crystals or powder

Uses

It finds its uses as a actinometer for the UV-A range of photostability testing of pharmaceuticals. 2-Nitrocinnamaldehyde can be oxidized to 2-nitrocinnamic acid which can be used in the Baeyer-Emmerling indole synthesis to produce indole and substituted indoles.

Synthesis Reference(s)

Tetrahedron Letters, 31, p. 4497, 1990 DOI: 10.1016/S0040-4039(00)97659-7

Check Digit Verification of cas no

The CAS Registry Mumber 1466-88-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,4,6 and 6 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1466-88:
(6*1)+(5*4)+(4*6)+(3*6)+(2*8)+(1*8)=92
92 % 10 = 2
So 1466-88-2 is a valid CAS Registry Number.
InChI:InChI=1/C9H7NO3/c11-7-3-5-8-4-1-2-6-9(8)10(12)13/h1-7H/b5-3+

1466-88-2 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (N0611)  2-Nitrocinnamaldehyde  >98.0%(GC)

  • 1466-88-2

  • 5g

  • 350.00CNY

  • Detail
  • TCI America

  • (N0611)  2-Nitrocinnamaldehyde  >98.0%(GC)

  • 1466-88-2

  • 25g

  • 990.00CNY

  • Detail
  • Alfa Aesar

  • (A10308)  2-Nitrocinnamaldehyde, predominantly trans, 98%   

  • 1466-88-2

  • 10g

  • 449.0CNY

  • Detail
  • Alfa Aesar

  • (A10308)  2-Nitrocinnamaldehyde, predominantly trans, 98%   

  • 1466-88-2

  • 25g

  • 968.0CNY

  • Detail
  • Alfa Aesar

  • (A10308)  2-Nitrocinnamaldehyde, predominantly trans, 98%   

  • 1466-88-2

  • 50g

  • 1845.0CNY

  • Detail

1466-88-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Nitrophenylacrolein

1.2 Other means of identification

Product number -
Other names 2-Propenal, 3-(2-nitrophenyl)-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1466-88-2 SDS

1466-88-2Relevant articles and documents

Dual-supramolecular contacts induce extreme Hofmann framework distortion and multi-stepped spin-crossover

Ahmed, Manan,Brand, Helen E. A.,Peterson, Vanessa K.,Clegg, Jack K.,Kepert, Cameron J.,Price, Jason R.,Powell, Benjamin J.,Neville, Suzanne M.

, p. 1434 - 1442 (2021)

An extended nitro-functionalised 1,2,4-triazole ligand has been used to induce considerable lattice distortion in a 2-D Hofmann framework materialviacompeting supramolecular interactions. Single crystal X-ray diffraction analyses on [Fe3(N-cintrz)6(Pd(CN)4)3]·6H2O (N-cintrz: (E)-3-(2-nitrophenyl)acrylaldehyde) reveal a substantial deviation from a regular Hofmann structure, in particular as the intra- and inter-layer contacts are dominated by hydrogen-bonding interactions rather than the typical π-stacking arrays. Also, the 2-D Hofmann layers show an assortment of ligand conformations and local FeIIcoordination environments driven by the optimisation of competing supramolecular contacts. Temperature-dependent magnetic susceptibility measurements reveal a two-step spin crossover (SCO) transition. Variable temperature structural analyses show that the two crystallographically distinct FeIIcentres, which are arranged in stripes (2?:?1 ratio) within each Hofmann layer, undergo a cooperative HS ? HS/LS ? LS (HS = high spin, LS = low spin) transition without periodic spin-state ordering. The mismatch between crystallographic (2?:?1) and spin-state (1?:?1) periodicity at the HS?:?LS step provides key insight into the competition (frustration) between elastic interactions and crystallographically driven order.

Sodium bismuthate mediated oxidation of allylic and benzylic alcohols

Banik, Bimal K.,Ghatak, Anjan,Venkatraman,Becker, Frederick F.

, p. 2701 - 2705 (2000)

A simple and readily available oxidation of primary allylic and benzylic alcohols to the corresponding aldehydes is carried out by sodium bismuthate in acetic acid.

(±)-Camphor sulfonic acid assisted IBX based oxidation of 1° and 2° alcohols

Kumar, Kamlesh,Joshi, Penny,Rawat, Diwan S

, (2021/09/02)

-

Enantiodivergent One-Pot Synthesis of Axially Chiral Biaryls Using Organocatalyst-Mediated Enantioselective Domino Reaction and Central-to-Axial Chirality Conversion

Hayashi, Yujiro,Koshino, Seitaro,Kwon, Eunsang,Monde, Kenji,Taniguchi, Tohru

, p. 15786 - 15794 (2021/10/14)

Enantiodivergent one-pot synthesis of biaryls was developed using a catalytic amount of a single chiral source. A domino organocatalyst-mediated enantioselective Michael reaction and aldol condensation provided centrally chiral dihydronaphthalenes with excellent enantioselectivity, from which an enantiodivergent chirality conversion from central-to-axial chirality was achieved. Both enantiomers of biaryls were obtained with excellent enantioselectivity. All transformations can be conducted in a single reaction vessel. A plausible reaction mechanism for the enantiodivergence is proposed.

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