146934-32-9

Basic information

• Product Name: 2-Azido-4,6-O-benzylidene-3-O-chloroacetyl-2-deoxy-β-D-glucopyranosyl chloride
• Synonyms: 2-Azido-4,6-O-benzylidene-3-O-chloroacetyl-2-deoxy-β-D-glucopyranosyl chloride
• CAS NO: 146934-32-9
• Molecular Weight: 388.207
• Mol File: 146934-32-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Azido-4,6-O-benzylidene-3-O-chloroacetyl-2-deoxy-β-D-glucopyranosyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Azido-4,6-O-benzylidene-3-O-chloroacetyl-2-deoxy-β-D-glucopyranosyl chloride(146934-32-9)
• EPA Substance Registry System: 2-Azido-4,6-O-benzylidene-3-O-chloroacetyl-2-deoxy-β-D-glucopyranosyl chloride(146934-32-9)

Safety Data

• Hazardous Substances Data: 146934-32-9(Hazardous Substances Data)

Upstream product

• 28140-37-6 3,4,6-tri-O-acetyl-1,2-O-(1-ethoxyethylidene)-β-D-mannopyranoside 
• 18968-05-3 1,3,4,6-tetra-O-acetyl-β-D-mannopyranose 
• 146934-27-2 Methyl 2-azido-2-deoxy-3,4,6-tri-O-acetyl-1-thio-α-D-glucopyranoside 
• 146934-30-7 Methyl 2-azido-4,6-O-benzylidene-2-deoxy-1-thio-α-D-glucopyranoside 
• 146934-29-4 Methyl 2-azido-2-deoxy-1-thio-α-D-glucopyranoside 
• 92051-23-5 1,3,4,6-tetra-O-acetyl-2-O-trifluoromethanesulfonyl-β-D-mannopyranose 
• 80321-89-7 1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy-β-D-glucopyranose 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 83-87-4 D-Mannose pentaacetate 
• 146934-31-8 Methyl 2-azido-4,6-O-benzylidene-3-O-chloroacetyl-2-deoxy-1-thio-α-D-glucopyranoside 

Relevant articles and documents

Synthesis of tetrasaccharide building block of the O-specific polysaccharide of Shigella dysenteriae type 1

A glycosyl trichloroacetimidate derivative (1) of the tetrasaccharide α-D-Galp-(1→3)-α-D-GlcpNAc-(1→3)-α-L-Rhap-(1→3)-α-L-Rhap was synthesized in a highly stereoselective, stepwise manner, using methyl 1-thioglycosides of L-rhamnose, 2-azido-2-deoxy-D-glucose and D-galactose, as major intermediates. The protecting group scenario in compound 1 permits regioselective deblocking at its 'non-reducing end' unit. Therefore 1 is a suitable intermediate for the preparation of extended fragments of the title polysaccharide.