14787-38-3

Basic information

• Product Name: 7-METHYL-JUGLONE
• Synonyms: 7-METHYL-JUGLONE;5-Hydroxy-7-methyl-1,4-naphthoquinone;6-Methyl-8-hydroxy-1,4-naphthoquinone;7-Methyl-5-hydroxynaphthalene-1,4-dione;Ramentaceone;7-Methyl-5-hydroxy-1,4-naphthoquinone;5-Hydroxy-7-methyll-,1,4-naphtoquinone;Aids108047
• CAS NO: 14787-38-3
• Molecular Formula: C₁₁H₈O₃
• Molecular Weight: 188.181
• Mol File: 14787-38-3.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 427.2°Cat760mmHg
• Flash Point: 226.3°C
• Appearance: /
• Density: 1.371g/cm³
• Vapor Pressure: 6.68E-08mmHg at 25°C
• Refractive Index: 1.642
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 7-METHYL-JUGLONE(CAS DataBase Reference)
• NIST Chemistry Reference: 7-METHYL-JUGLONE(14787-38-3)
• EPA Substance Registry System: 7-METHYL-JUGLONE(14787-38-3)

Safety Data

• Hazardous Substances Data: 14787-38-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 3766, 1984 DOI: 10.1021/jo00194a017

InChI:InChI=1/C11H8O3/c1-6-4-7-8(12)2-3-9(13)11(7)10(14)5-6/h2-5,14H,1H3

Upstream product

• 69945-30-8 5,8-Diacetoxy-2-acetyl-4-chlor-3-methyl-1-naphthol 
• 1130-61-6 1,8-Dihydroxy-3-methylnaphthalin 

Downstream Products

• 86377-54-0 ismailin 
• 3300-25-2 8-O-methylchrysophanol 
• 76695-93-7 1-hydroxy-5-methoxy-3-methyl-9,10 dihydroanthracene 9,10-dione 
• 33916-25-5 neodiospyrin 
• 518-82-1 1,6,8-trihydroxy-3-methyl-9,10-anthraquinone 
• 521-61-9 physcion 
• 161811-59-2 2-bromo-8-hydroxy-6-methyl-1,4-naphthoquinone 
• 273200-81-0 2-bromo-5-hydroxy-7-methyl-1,4-naphthoquinone 
• 1255790-44-3 C₄₆H₅₅NO₈Si 
• 1330578-86-3 C₄₃H₄₉NO₈ 
• 1255790-45-4 C₄₃H₄₉NO₈ 
• 1330578-79-4 8-benzyloxy-2,3-dibromo-4,4-dimethoxy-6-methylnaphthalene 
• 1255790-42-1 tert-butyl (1R,3R,4S,5R)-1-(4'-(8'-(5''-benzyloxy-2'',3''-dibromo-1''-methoxy-7''-methylnaphthalen-4''-yloxy)ethyldimethylsilyl)furan-1'-yl)-4-benzyloxy-tetrahydro-5-methyl-2H-pyran-3-ylmethylcarbamate 
• 1255790-43-2 8-benzyloxy-2,3-dibromo-4-methoxy-6-methylnaphthalen-1-ol 

Relevant articles and documents

Catalyst-Controlled Transannular Polyketide Cyclization Cascades: Selective Folding of Macrocyclic Polyketides

The biomimetic synthesis of aromatic polyketides from macrocyclic substrates by means of catalyst-controlled transannular cyclization cascades is described. The macrocyclic substrates, which feature increased stability and fewer conformational states, were thereby transformed into several distinct polyketide scaffolds. The catalyst-controlled transannular cyclizations selectively led to aromatic polyketides with a defined folding and oxygenation pattern, thus emulating β-keto-processing steps of polyketide biosynthesis.