14933-91-6

Basic information

• Product Name: N-(phenylsulfanyl)aniline
• Synonyms: Benzenesulfenamide, N-phenyl-; N-Phenyl-benzene-sulphenamide
• CAS NO: 14933-91-6
• Molecular Formula: C₁₂H₁₁NS
• Molecular Weight: 201.2874
• Mol File: 14933-91-6.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 322°C at 760 mmHg
• Flash Point: 148.5°C
• Density: 1.16g/cm³
• Vapor Pressure: 0.000288mmHg at 25°C
• Refractive Index: 1.653
• CAS DataBase Reference: N-(phenylsulfanyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-(phenylsulfanyl)aniline(14933-91-6)
• EPA Substance Registry System: N-(phenylsulfanyl)aniline(14933-91-6)

Safety Data

• Hazardous Substances Data: 14933-91-6(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 931-59-9 benzenesulfenyl chloride 
• 882-33-7 diphenyldisulfane 
• 28833-58-1 C₂₄H₂₀N₂O₄S₄ 
• 108-98-5 thiophenol 
• 586-96-9 Nitrosobenzene 
• 258822-89-8 3-Phenylsulfenyl-2-(N-cyanoimino)thiazolidine 
• 622-38-8 Ethyl phenyl sulfide 
• 622-37-7 Phenyl azide 
• 103375-25-3 S-Isopropyl-N,S-diphenyl-sulfimid 
• 28074-23-9 phenylsulfenyl bromide 
• 14204-35-4 5,5-Dimethyl-3-phenylthiohydantoin 
• 88047-06-7 N-phenylbis(benzenesulphen)amide 
• 14204-27-4 N-phenylthiophthalimide 

Downstream Products

• 93-98-1 N-phenyl benzoyl amide 
• 882-33-7 diphenyldisulfane 
• 115011-49-9 trans-1-benzamido-2-(phenylthio)cyclohexane 
• 115022-91-8 N--N'-phenylbenzamidine 
• 91525-58-5 Phenyl-(2-phenylsulfanyl-cyclohexyl)-amine 
• 88047-04-5 N-phenyl-N'-phenylthio-p-phenylenediamine 
• 101-54-2 N-phenylphenylene-1,4-diamine 
• 54705-90-7 (2-nitro-thiophen-3-yl)-phenyl-amine 
• 19985-30-9 N-(5-Nitro-2-thienyl)aniline 
• 1135-14-4 4-aminophenyl phenyl sulfide 
• 78945-05-8 S-phenyl pent-4-enethioate 
• 108-98-5 thiophenol 
• 28215-02-3 (2-nitro-phenyl)-phenyl disulfide 
• 34690-49-8 N,N-(Diphenyl)benzenesulfenamide 

Relevant articles and documents

Flavin/I2 catalyzed aerobic oxidative C–H sulfenylation of anilines

A flavin/I2 catalyzed aerobic oxidative C–H sulfenylation of anilines with thiols under mild reaction conditions is presented for the first time. This metal-free reaction provides an atom-economic pathway to prepare various aryl sulfides with outstanding functional group compatibility. Moreover, it consumes molecular oxygen as the only terminal oxidant and produces environmentally-friendly H2O as the only byproduct.

Imination of sulfur-containing compounds: XXXVI. A new method of synthesis and oxidative arylsulfonylimination of sulfenamides

Sulfenylation of ammonia, amines, and arenesulfonamide sodium salts with N-(arylsulfenyl)-N,N′-bis(arylsulfonyl)sulfinimidamides afforded unsubstituted and N-substituted arenesulfenamides. Oxidation of the latter with N-chloro sulfonamide sodium salts gav

Nitroarylamines via the Vicarious Nucleophilic Substitution of Hydrogen: Amination, Alkylamination, and Arylamination of Nitroarenes with Sulfenamides

A new reaction of sulfenamides with electrophilic arenes under basic conditions is described. The σ adducts formed from nitroarenes and the anions of sulfenamides undergo elimination of thiol to produce the corresponding o- and/or p-nitroanilines. This reaction is analogous to the known alkylation and hydroxylation of nitroarenes via the vicarious nucleophilic substitution of hydrogen (VNS). The reaction gives access to a wide range of substituted nitroanilines, nitronaphthylamines, and aminoheterocycles. By means of the reaction with N-alkyl- and N-arylsulfenamides, it is possible to obtain N-alkylnitroanilines and nitrodiarylamines. By varying the structure of sulfenamide and the reaction conditions, particularly the nature and concentration of the base, it is possible to control the orientation of animation.