14933-95-0

Basic information

• Product Name: Benzenesulfenamide, N-(4-chlorophenyl)-
• CAS NO: 14933-95-0
• Molecular Formula: C12H10ClNS
• Molecular Weight: 235.737
• Mol File: 14933-95-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenesulfenamide, N-(4-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfenamide, N-(4-chlorophenyl)-(14933-95-0)
• EPA Substance Registry System: Benzenesulfenamide, N-(4-chlorophenyl)-(14933-95-0)

Safety Data

• Hazardous Substances Data: 14933-95-0(Hazardous Substances Data)

Upstream product

• 106-47-8 4-chloro-aniline 
• 931-59-9 benzenesulfenyl chloride 
• 103375-31-1 C₁₅H₁₆ClNS 
• 108-98-5 thiophenol 

Downstream Products

• 91525-63-2 threo-2-(phenylthio)-3-(4-chlorophenylamino)butane 
• 106-47-8 4-chloro-aniline 
• 882-33-7 diphenyldisulfane 
• 3372-79-0 2,7-dichloro-phenazine 
• 124251-52-1 N-(4-chlorophenyl)-N'-<1-(phenylthio)hex-1-en-2-yl>acetamidine 
• 124251-53-2 N-(4-chlorophenyl)-N'-<3-(phenylthio)but-2-en-2-yl>acetamidine 
• 124251-54-3 N-(4-chlorophenyl)-N'-<2-(phenylthio)hex-2-en-3-yl>acetamidine 
• 124251-55-4 N-(4-chlorophenyl)-N'-<3-(phenylthio)hex-2-en-2-yl>acetamidine 
• 91525-63-2 erythro-2-(phenylthio)-3-(4-chlorophenylamino)butane 
• 13065-93-5 4-amino-4'-chlorodiphenylamine 
• 91525-57-4 trans-1-(phenylthio)-2-(4-chlorophenylamino)cyclohexane 
• 105416-98-6 1-(phenylthio)-2-(4-chlorophenylamino)-2-methylpropane 
• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 88047-08-9 N-(p-chlorophenyl)-N'-phenylthio-p-benzoquinone di-imine 

Relevant articles and documents

LDA-promoted decomposition of benzenesulfenamides. A route to aminyl radicals by dioxygen oxidation of lithium amides

The LDA-promoted decomposition of N-monosubstituted sulfenamides 1a-d occurs through the formation of thioaminyl anions, which undergo oxidation either at sulfur, with formation of sulfonamides, or at nitrogen, with formation of thioaminyl radicals, depending on the nature of the 4'-substituent. The reaction of N,N-disubstituted sulfenamides 1e-h proceeds through the intermediacy of a lithium complex capable of generating aminyl radicals via sulfenyl group transfer to the di-iso-propylamido anion and subsequent aerial oxidation of the resulting lithium amides 3e-h.

Alkyl- and Arylsulfenanilides by Cycloelimination of Propene from N-Aryl-S-isopropyl-sulfimides

A series of N-aryl-S-isopropyl-S-alkyl- or aryl-sulfimides has been prepared and transformed into alkyl- or arylsulfenanilides, respectively, by thermal cycloelimination of propene. - Keywords: Sulfimides; Sulfenanilides; Thermolysis; Cycloelimination.