150749-03-4

Basic information

• Product Name: Acetic acid, [[(1,1-dimethylethoxy)carbonyl]amino]hydroxy-, methyl ester (9CI)
• Synonyms: Acetic acid, [[(1,1-dimethylethoxy)carbonyl]amino]hydroxy-, methyl ester (9CI)
• CAS NO: 150749-03-4
• Molecular Formula: C₈H₁₅NO₅
• Molecular Weight: 205.2084
• Product Categories: N-BOC
• Mol File: 150749-03-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Acetic acid, [[(1,1-dimethylethoxy)carbonyl]amino]hydroxy-, methyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [[(1,1-dimethylethoxy)carbonyl]amino]hydroxy-, methyl ester (9CI)(150749-03-4)
• EPA Substance Registry System: Acetic acid, [[(1,1-dimethylethoxy)carbonyl]amino]hydroxy-, methyl ester (9CI)(150749-03-4)

Safety Data

• Hazardous Substances Data: 150749-03-4(Hazardous Substances Data)

Upstream product

• 4248-19-5 tert-butyl carbazate 
• 109745-70-2 methyl glyoxylate methyl hemi-acetal 
• 6000-59-5 glyoxalic acid monohydrate 

Downstream Products

• 106928-50-1 methyl 2-[(tert-butoxycarbonyl)amino]pent-4-enoate 
• 51987-73-6 methyl 2-tert-butoxycarbonylamino-3-phenylpropanoate 
• 71460-02-1 methyl 2-[((1,1-dimethylethoxy)carbonyl)amino]-4-pentynoate 
• 103711-23-5 α-<(tert-butyloxycarbonyl)amino>-N^α-(benzyloxycarbonyl)glycine 
• 103711-24-6 α-(tert-butyloxycarbonylamino)-N^α-(benzyloxycarbonyl)glycine methyl ester 
• 103711-29-1 Amino-tert-butoxycarbonylamino-acetic acid methyl ester 
• 42726-79-4 methyl N-t-butoxycarbonyl-α-benzylthioglycinate 
• 121056-95-9 trimethyl 2-(tert-butoxycarbonylamino)phosphonoacetate 

Relevant articles and documents

Synthesis of a naturally occurring diene-containing amino acid and its glutamyl dipeptide via N-acyliminium ion chemistry

The syntheses of the naturally occurring unusual unsaturated amino acid (S)-2-amino-3-methylene-4-pentenoic acid and the corresponding γ-glutamyl dipeptide are described. Key steps are an N-acyliminium ion addition using allenylmethylsilane as nucleophile and an enzymatic resolution mediated by the L-aminopeptidase from Pseudomonas putida. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.

Zinc mediated addition of active halides to a glycine cation equivalent: Synthesis of N-Boc-L-propargylglycine

The reaction of allylic, benzylic and propargylic halides with zine in the presence of the glycine cation equivalent, methyl N-Boc-2-acetoxyglycine, affords Boc protected amino acid derivatives in high yield. Resolution of methyl N-Boc- propargylglycine w