15575-04-9Relevant articles and documents
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Rueegg et al.
, p. 2616,2619 (1959)
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Synthesis and spectroscopic characterisation of 13C-labelled ubiquinone-0 and ubiquinone-10
Liemt, W. B. S. van,Steggerda, W. F.,Esmeijer, R.,Lugtenburg, J.
, p. 153 - 162 (2007/10/02)
(1-13C)-, (2-13C)-, (3-13C)-, (3-13CH3)-, (4-13C)-, and (13CH3O)2-ubiquinone-10 and the corresponding (1-13C)-, (6-13C)-, (5-13C)-, (5-13CH3)-, (4-13C)-, and (13CH3O)2-ubiquinone-0 have been synthesised from simple labelled starting materials via a single reaction scheme.The ubiquinones have been characterised using mass spectrometry, 1H NMR and 13C NMR.The spectroscopic results indicate that, within experimental error, the syntheses have been accomplished without scrambling or dilution of label.All labelled ubiquinones have been synthesised on a decigram scale.
SYNTHESIS OF all-(E)-DECAPRENOL AND ITS 2Z ISOMER
Kozlova, I. V.,Obol'nikova, E. A.,Kogan, L. M.,Filippova, T. M.,Kharchevnikov, A. P.,Samokhvalov, G. I.
, p. 1055 - 1061 (2007/10/02)
C5-chain growth in the structure of natural solanesol, isolated from tobacco, was realized by a C3 + C2 scheme.Decaprenol was separated into isomers with respect to the newly formed double bond by column chromatography on silica gel.The isomeric compositi
