157428-86-9

Basic information

• Product Name: N-(but-3-enyl)-2-cyanobenzenamine
• Synonyms: N-(but-3-enyl)-2-cyanobenzenamine
• CAS NO: 157428-86-9
• Molecular Weight: 172.23
• Mol File: 157428-86-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(but-3-enyl)-2-cyanobenzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(but-3-enyl)-2-cyanobenzenamine(157428-86-9)
• EPA Substance Registry System: N-(but-3-enyl)-2-cyanobenzenamine(157428-86-9)

Safety Data

• Hazardous Substances Data: 157428-86-9(Hazardous Substances Data)

Upstream product

• 5162-44-7 1-bromo-4-butene 
• 1885-29-6 anthranilic acid nitrile 

Downstream Products

• 157428-90-5 2-(but-3'-enylamino)benzylamine 
• 28736-12-1 2-<(but-3'-enyl)amino>benzamide 
• 72752-52-4 2-(piperidin-1-yl)benzonitrile 

Relevant articles and documents

The Stereochemistry of Organometallic Compounds. XL. Rhodium-Catalysed Reactions of Hydrogen and Carbon Monoxide with Alkenylanilines

Rhodium-catalysed reactions of o- or p-cyano-N-allylanilines with H2/CO give N-arylpyrrolidine aldehydes resulting from a double hydroformylation sequence.In contrast reactions of o- or p-methyl-N-allylanilines or N-allylaniline itself with H2/CO give 'dimeric' compounds resulting from self-condensation reactions of an initially formed hydroformylation product together with varying amounts of the double hydroformylation product.Similar reactions of o-cyano-N-but-3-enylanilines give low yields of double hydroformylation products and major products arising from hydrogenation or cross coupling of intermediate enamines.The structure of one of these products, N-2-cyanophenyl-5-(N'-2-cyanophenyl-3-methylpyrrolidin-2-yl)-1,2,3,4-tetrahydropyridine (17) (IUPAC name: 2--1,2,3,4-tetrahydropyridin-1-yl>benzonitrile) was confirmed by an X-ray single-crystal structure determination.