157474-53-8Relevant articles and documents
Unusual reagent control of diastereoselectivity in the 1,2-addition of hard carbon nucleophiles to C(6)-heteroatom substituted cyclohexenones.
Lindsay,Salisbury,Cordes,McIntosh
, p. 4007 - 4010 (2001)
[reaction: see text] A surprising and synthetically useful counterion-dependent reversal of diastereoselectivity was found in 1,2-additions of hard carbon nucleophiles to C(6)-heterosubstituted cyclohexenones. In general, Grignard reagents added syn to th
Metal-Catalyzed Organic Photoreactions. Chemo- and Regioselectivities in the CuCl2-Induced Photooxidation of Olefins.
Sato, Tadashi,Yonemochi, Shin-ichi
, p. 7375 - 7384 (2007/10/02)
Copper(II) chloride induced the chemo and regioselective chlorohydroperoxidation, as well as the site-selective chlorination of olefins, under photooxygenation conditions.