1585-45-1

Basic information

• Product Name: N-(diphenylmethylidene)benzamide
• CAS NO: 1585-45-1
• Molecular Formula: C₂₀H₁₅NO
• Molecular Weight: 285.3392
• Mol File: 1585-45-1.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 441.5°C at 760 mmHg
• Flash Point: 182.2°C
• Density: 1.05g/cm³
• Vapor Pressure: 5.43E-08mmHg at 25°C
• Refractive Index: 1.586
• CAS DataBase Reference: N-(diphenylmethylidene)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(diphenylmethylidene)benzamide(1585-45-1)
• EPA Substance Registry System: N-(diphenylmethylidene)benzamide(1585-45-1)

Safety Data

• Hazardous Substances Data: 1585-45-1(Hazardous Substances Data)

Upstream product

• 108-75-8 2,4,6-trimethyl-pyridine 
• 98-88-4 benzoyl chloride 
• 100-47-0 benzonitrile 
• 1485-72-9 N-benzoyl-diphenylmethylamine 
• 78074-95-0 S-trimethylsilyl benzophenone thiooxime 
• 1013-88-3 Benzophenone imine 
• 108-86-1 bromobenzene 
• 857796-74-8 N-(2,3-dioxo-1,1,3-triphenyl-propyl)-N-methoxy-benzamide 
• 124-41-4 sodium methylate 
• 983-79-9 benzophenone azine 
• 93-89-0 benzoic acid ethyl ester 
• 17599-59-6 diphenylmethyleneaminotrimethylsilane 
• 108-48-5 2,6-dimethylpyridine 
• 5319-67-5 diphenylmethanimine hydrochloride 

Downstream Products

• 35027-18-0 N-(2-Cyano-2,2-dimethyl-1,1-diphenyl-ethyl)-benzamide 
• 35027-12-4 N-(2-Cyano-1,1-diphenyl-hexyl)-benzamide 
• 35027-11-3 N-(2-Cyano-3-methyl-1,1-diphenyl-butyl)-benzamide 
• 35027-10-2 N-(2-Cyano-1,1-diphenyl-pentyl)-benzamide 
• 39057-70-0 tert-butyl-(2,4,4-triphenyl-4H-oxazol-5-ylidene)-amine 
• 35027-21-5 N-[(1-Cyano-cyclobutyl)-diphenyl-methyl]-benzamide 
• 35027-20-4 N-[(1-Cyano-cyclopropyl)-diphenyl-methyl]-benzamide 
• 35027-08-8 2-Methyl-3-benzamino-3,3-diphenyl-propionitril 
• 35027-32-8 N-[(1,4-Dicyano-cyclohexyl)-diphenyl-methyl]-benzamide 
• 35027-33-9 C₄₈H₄₀N₄O₂ 
• 35364-02-4 2-(4-chlorophenyl)-3,3-diphenylacrylonitrile 
• 35027-16-8 N-[2-(4-Chloro-phenyl)-2-cyano-1,1-diphenyl-ethyl]-benzamide 
• 119-61-9 benzophenone 
• 55-21-0 benzamide 

Relevant articles and documents

Synthesis and characterization of new ca-disubstituted (diarylaminomethyl)phosphonates

A convenient and efficient three-step procedure for the preparation of W-protected or unprotected C-disubstituted (di-arylaminomethyOphosphonates 1 is reported. This method allows diversification of the substituents on the carbon in the a-position to the phosphorus, as well as the protective group on the amine and the phosphonate ester group.

N-Acyl-α-imino Acid Derivatives, II. - Synthesis of N-Acylimines of Methyl Phenylglyoxylate

The title compounds 8 are obtainable via treatment of phenylglycine methyl ester (2) with tert-butyl hypochlorite or by direct dehydrogenation of the N-acylphenylglycine ester 6 with N-bromosuccinimide.

PYRIDINES, PARTIE X - SYNTHESE DE PYRIDYL- ET QUINOLYLENAMIDINES PAR CONDENSATION ENTRE COMPOSES ORGANOLITHIENS ET BENZONITRILE. NOVEAUX INTERMEDIAIRES POUR REACTIONS D'HETEROCYCLISATION

A series of methylpyridyl- and (methyl)quinolylphenylvinylbenzamidines has been synthesized by condensation of organopolylithium compounds derived from polymethylpyridines and quinolines with benzonitrile.In diethyl ether, besides the enamidines, the reaction gives enolizable ketones.Triphenylimidazole, triphenyl-s-triazine and triphenylpyrimidine are isolated in the case of benzylmagnesium chloride.Possible routes leading to the various products are suggested.In diethyl ether, the conditions wich give the enamidine derivatives in useful yields have been established.In liquid ammonia, on the contrary, no polycondensed products were isolated.The intermediate enamine and enamidine anions are trapped in diethyl ether by acetylation of the reaction mixture before hydrolysis.With benzoyl or acetyl chloride, ethyl chloroformate, various C- and N-acylated products (enolizable β-diketones, enamides, acylenamides, N-acylenamidines) and their cyclization products (pyrimidines) are obtained.The latter are also prepared from the isolated enamidines and benzoyl chlorides.