1595-10-4

Basic information

• Product Name: Benzene, 1-hexyl-2-methyl-
• CAS NO: 1595-10-4
• Molecular Formula: C13H20
• Molecular Weight: 176.302
• Mol File: 1595-10-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzene, 1-hexyl-2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-hexyl-2-methyl-(1595-10-4)
• EPA Substance Registry System: Benzene, 1-hexyl-2-methyl-(1595-10-4)

Safety Data

• Hazardous Substances Data: 1595-10-4(Hazardous Substances Data)

Upstream product

• 615-37-2 ortho-methylphenyl iodide 
• 542-69-8 1-iodo-butane 
• 592-41-6 1-hexene 
• 1134-92-5 o-tolyl N,N-dimethylsulfamate 
• 44767-62-6 n-hexylmagnesium chloride 
• 16343-08-1 hexylboronic acid 
• 95-49-8 2-methylchlorobenzene 
• 74-85-1 ethene 
• 108-88-3 toluene 
• 111-27-3 hexan-1-ol 
• 16419-60-6 2-Methylphenylboronic acid 
• 3839-35-8 4-methylbenzenesulfonic acid n-hexylester 
• 91994-11-5 5,5-dimethyl-2-(o-tolyl)-1,3,2-dioxaborinane 
• 1202873-13-9 1-hexyl-2-methyl-2,5-cyclohexadiene-1-carboxylic acid 

Relevant articles and documents

Nickel metallodendrimers as catalyst precursors in the tandem oligomerization of ethylene and Friedel-Crafts alkylation of its olefinic products Metallodendrimers Special Issue

The synthesis and catalytic activity of nickel metallodendrimers (C1-C6) are reported. The metallodendrimers were synthesized by the coordination of the metal precursors, Ni(OAc)2 and Ni(DME)Br2, to the periphery of salicylaldimine and iminopyridyl modified dendritic ligands, DL1-DL6, based on the generation 1 to generation 3 diaminobutane polypropylene imine (DAB-PPI) dendrimers. The metallodendrimers were tested in the oligomerization of ethylene and were found to be active catalysts. When using this catalyst system, it was found that a tandem process occurred in which ethylene oligomerization was followed by Friedel-Crafts alkylation of the reaction solvent, toluene. The latter process is mediated by the aluminium co-catalyst, EtAlCl2.

Visible-Light-Induced Nickel-Catalyzed Cross-Coupling with Alkylzirconocenes from Unactivated Alkenes

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Copper-catalyzed cross-coupling reaction of organoboron compounds with primary alkyl halides and pseudohalides

Non-activated alkyl electrophiles, including alkyl iodides, bromides, tosylates, mesylates, and even chlorides, underwent copper-catalyzed cross-coupling with aryl boron compounds and alkyl 9-BBN reagents (see scheme; 9-BBN=9-borabicyclo[3.3.1]nonane). The reactions proceed with practically useful reactivities and thus complement palladium- and nickel-catalyzed Suzuki-Miyaura coupling reactions of alkyl halides.