1603837-65-5

Basic information

• Product Name: 6-(3-chlorophenyl)-2-methylphenanthridine
• Synonyms: 6-(3-chlorophenyl)-2-methylphenanthridine
• CAS NO: 1603837-65-5
• Molecular Weight: 303.791
• Mol File: 1603837-65-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 6-(3-chlorophenyl)-2-methylphenanthridine(CAS DataBase Reference)
• NIST Chemistry Reference: 6-(3-chlorophenyl)-2-methylphenanthridine(1603837-65-5)
• EPA Substance Registry System: 6-(3-chlorophenyl)-2-methylphenanthridine(1603837-65-5)

Safety Data

• Hazardous Substances Data: 1603837-65-5(Hazardous Substances Data)

Upstream product

• 583-68-6 2-bromo-p-toluidine 
• 98-80-6 phenylboronic acid 
• 1428264-89-4 2-isocyano-5-methyl-1,1'-biphenyl 
• 108-42-9 3-chloro-aniline 
• 1428264-96-3 C₁₄H₁₃NO 
• 42308-28-1 2-amino-5-methylbiphenyl 

Relevant articles and documents

Catalyst-free synthesis of phenanthridinesviaelectrochemical coupling of 2-isocyanobiphenyls and amines

Catalyst free synthesis of 6-aryl phenanthridines and amides through an electrochemical reaction is reported in this study. The coupling reaction proceeds by the cathodic reduction ofin situformed diazonium ions, which are formed from anilines and an alkyl nitrite. The generated aryl radical diazonium ions coupled from isocyanides furnished the desired products in good yields. This cascade reaction was conducted in an undivided cell equipped with an RVC as the anode and Pt as the cathode usingnBu4NBF4as the electrolyte at room temperature. A series of detailed mechanistic studies have also been performed, including a radical clock experiment and cyclic voltammetry analysis.