166023-25-2Relevant articles and documents
Chiral ligand-controlled asymmetric conjugate amination of enoates with lithium mesitylmethyl(trimethylsilyl)amide
Sakai, Takeo,Doi, Hirohisa,Tomioka, Kiyoshi
, p. 8351 - 8359 (2007/10/03)
Lithium mesitylmethyl(trimethylsilyl)amide behaved as a nice amination agent in a chiral ligand-controlled conjugate addition reaction of tert-butyl cinnamate to give the conjugate amination product with 99% ee in 90% yield. Other acyclic and cyclic enoat