166185-34-8

Basic information

• Product Name: Mo(S₂C₂H(C₆H₄OCH₃))3
• CAS NO: 166185-34-8
• Molecular Weight: 684.822
• Mol File: 166185-34-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mo(S₂C₂H(C₆H₄OCH₃))3(CAS DataBase Reference)
• NIST Chemistry Reference: Mo(S₂C₂H(C₆H₄OCH₃))3(166185-34-8)
• EPA Substance Registry System: Mo(S₂C₂H(C₆H₄OCH₃))3(166185-34-8)

Safety Data

• Hazardous Substances Data: 166185-34-8(Hazardous Substances Data)

Upstream product

• 7631-95-0 sodium molybdate dihydrate 

Relevant articles and documents

Synthesis, Cyclic Voltammetric and Electrospray Mass Spectrometric Studies of a Series of Tris-Substituted 1,2-Dithiolene Complexes of Tungstenand Molybdenum

Ten new nonsymmetric dithiolenes of the general formula [RR'(C2S2)]3M were synthesized, from the corresponding 1,3-dithiol-2-ones, or from the corresponding mixed benzoins and tetraphosphorus decasulfide. The redox properties of these ten complexes together with those of the symmetric ones with R = R' = Ph and M = Mo or W, were investigated by cyclic voltammetry. Two processes were only observed, assigned to C C(1-) and C(1-) C(2-) (C the complex), for which the quasi-reversible E1/2 potentials are highly dependent on the nature of the central metal ion, and for the same metal on the nature of the ligand and on the substituents on the phenyl rings. The ease by which the complexes are reduced is most likely the reason they give ESMS (negative mode) spectra, in spite of the fact they are neutral in solution. The process of this reduction and the parameters affecting it are investigated and discussed.