17015-63-3

Basic information

• Product Name: (+/-)-bakuchiol methyl ether
• Synonyms: (+/-)-bakuchiol methyl ether
• CAS NO: 17015-63-3
• Molecular Weight: 270.415
• Mol File: 17015-63-3.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: (+/-)-bakuchiol methyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-bakuchiol methyl ether(17015-63-3)
• EPA Substance Registry System: (+/-)-bakuchiol methyl ether(17015-63-3)

Safety Data

• Hazardous Substances Data: 17015-63-3(Hazardous Substances Data)

Upstream product

• 17015-62-2 3-(β-(p-Methoxyphenyl)-β-hydroxyethyl)-3,7-dimethyl-Δ^1,6-octadien 
• 1217536-40-7 (R)-1-(4-Methoxy-phenyl)-3,7-dimethyl-3-vinyl-octane-1,7-diol 
• 1020108-56-8 (3S)-3-ethenyl-1-(4-methoxyphenyl)-3,7-dimethyloct-6-en-2-yl methanesulfonate 
• 60699-32-3 (E)-3,7-dimethylocta-2,6-dien-1-yl diethyl phosphate 
• 768-60-5 4-methoxyphenylacetylen 
• 123-11-5 4-methoxy-benzaldehyde 
• 24470-78-8 isopropyltriphenylphosphonium iodide 
• 80-59-1 Tiglic acid 
• 485385-65-7 (S)-2-ethenyl-2,6-dimethylhept-5-en-1-ol 
• 1492057-03-0 C₂₇H₃₈OSi 
• 1492057-02-9 (S)-((2-(2-bromoethyl)-2-methylbut-3-en-1-yl)oxy)(tert-butyl)diphenylsilane 
• 1492057-01-8 (S)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-en-1-ol 
• 1492056-99-1 (S)-tert-butyl 3-(((tert-butyldiphenylsilyl)oxy)methyl)-3-methylpent-4-enoate 
• 1492056-88-8 (S)-tert-butyl 3-(hydroxymethyl)-3-methylpent-4-enoate 

Downstream Products

• 17015-60-0 bakuchiol 
• 74921-97-4 2-hydroxybakuchiol methyl ether 
• 1020108-62-6 4-[(1E,3R)-3-ethenyl-3,7-dimethylocta-1,6-dienyl]phenol 
• 1234320-94-5 (S)-4-{3-(4-methoxystyryl)-3,7-dimethylocta-1,6-dienyl}phenol 
• 1361320-55-9 1-methoxy-[4-{3-(4-methoxystyryl)-3,7-dimethylocta-1,6-dienyl}]benzene 
• 1361320-50-4 (S)-4-{3-(4-methoxystyryl)-3,7-dimethylocta-1,6-dienyl}phenol 
• 43010-56-6 8-Acetoxy-hexahydrobakuchiol-methylether 
• 43010-57-7 2,3,16,17-Tetrahydrobakuchiol-methylether 
• 54154-47-1 1-((1R,2S,5R)-2-Isopropyl-5-methyl-5-vinyl-cyclohexyl)-4-methoxy-benzene 
• 54154-48-2 1-((1S,2R,5R)-2-Isopropyl-5-methyl-5-vinyl-cyclohexyl)-4-methoxy-benzene 
• 54154-49-3 1-((1R,2S)-2-Isopropyl-5,5-dimethyl-cyclohexyl)-4-methoxy-benzene 
• 54274-55-4 1-((1S,2R)-2-Isopropyl-5,5-dimethyl-cyclohexyl)-4-methoxy-benzene 
• 54154-50-6 1-((R)-2-Isopropyl-5-methyl-5-vinyl-cyclohex-1-enyl)-4-methoxy-benzene 
• 43010-55-5 Hexahydrobakuchiol-methylether 

Relevant articles and documents

Regioselective molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: Methodology development and applications

The first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophiles is described. The method employs a readily accessible catalyst (Mo(CO)6/2,2′-bipyridine, both are commercially available) and represents the first example of the use of a group 6 transition metal-catalyst for allylic sulfonylation of substituted tertiary allylic electrophiles to form carbon-sulfur bonds. This atom economic and operationally simple methodology is characterized by its relatively mild conditions, wide substrate scope, and excellent regioselectivity profile, thus unlocking a new platform to forge sulfone moieties, even in the context of late-stage functionalization and providing ample opportunities for further derivatization through traditional Suzuki cross-coupling reactions.

Enantioselective Synthesis of Quaternary Stereocenters via Chromium Catalysis

Asymmetric allylation of aldehydes with γ-disubstituted allyl halides has been achieved in the presence of a sulfonamide/oxazoline chromium complex. A variety of synthetically useful α-homoallylic alcohols with two consecutive stereogenic centers, including one quaternary carbon, can be accessed in a highly diastereoselective and enantioselective manner.