171411-70-4

Basic information

• Product Name: [1S,3S,5S,6S]-3-(tert-butyldiphenylsilyloxymethyl)-9-oxo-5-phenylsulfonyl-2,7-dioxabicyclo[4.3.0]nonane
• Synonyms: [1S,3S,5S,6S]-3-(tert-butyldiphenylsilyloxymethyl)-9-oxo-5-phenylsulfonyl-2,7-dioxabicyclo[4.3.0]nonane
• CAS NO: 171411-70-4
• Molecular Weight: 552.764
• Mol File: 171411-70-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [1S,3S,5S,6S]-3-(tert-butyldiphenylsilyloxymethyl)-9-oxo-5-phenylsulfonyl-2,7-dioxabicyclo[4.3.0]nonane(CAS DataBase Reference)
• NIST Chemistry Reference: [1S,3S,5S,6S]-3-(tert-butyldiphenylsilyloxymethyl)-9-oxo-5-phenylsulfonyl-2,7-dioxabicyclo[4.3.0]nonane(171411-70-4)
• EPA Substance Registry System: [1S,3S,5S,6S]-3-(tert-butyldiphenylsilyloxymethyl)-9-oxo-5-phenylsulfonyl-2,7-dioxabicyclo[4.3.0]nonane(171411-70-4)

Safety Data

• Hazardous Substances Data: 171411-70-4(Hazardous Substances Data)

Upstream product

• 256343-19-8 [2S,3R,4S,6S]-6-(tert-butyldiphenylsilyloxymethyl)-3-(3-phenyl-2-propenyloxy)-4-phenylsulfonyl-2-(2-thiopyridyl)tetrahydro-2H-pyran 
• 171411-67-9 [2S,3R,4S,6S]-6-(tert-butyldiphenylsilyloxymethyl)-3-hydroxy-4-phenylsulfonyl-2-(2-thiopyridyl)tetrahydro-2H-pyran 
• 171411-65-7 [2S,4S]-2-(tert-butyldiphenylsilyloxymethyl)-4-phenylsulfonyl-3,4-dihydro-2H-pyran 
• 256343-23-4 (3aS,5S,7S,7aS)-7-Benzenesulfonyl-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furo[3,2-b]pyran-3-one 

Downstream Products

• 171411-71-5 [4S,6S,1'R]-2-(tert-butyldiphenylsilyloxymethyl)-6-(1,2-dihydroxyethyl)-3,6-dihydro-2H-pyran 
• 107573-28-4 2-Deoxy-β-KDO 
• 256343-21-2 [2R,3R,4S,6S,1'R]-3,4:1',2'-diisopropylidene-6-(tert-butyldiphenylsilyloxymethyl)-3,4-dihydroxy-2-(1,2-dihydroxyethyl)tetrahydro-2H-pyran 

Relevant articles and documents

Template-directed intramolecular C-glycosidation. Formation of tetrahydrofurans and application to the synthesis of a higher-order sugar

Cation-mediated cyclisation reactions of silyl enol ether-containing thioglycosides give bicyclic ketotetrahydrofurans. Cyclisation of an analogous 3-phenyl-2-propenyl ether-containing substrate gives an intermediate in the total synthesis of the higher-order sugar 2,3-dideoxy-D- manno-2-octulopyranosonic acid.