174063-87-7

Basic information

• Product Name: 1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene
• Synonyms: 1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-Methylbenzene 4-(3-Acryloyloxypropyloxy)-benzoesure -2-Methyl-1, 4-phenylester;2-Methyl-1,4-phenylene-bis[4[3(acryloyloxy)propyloxy]benzoate];4-(3-Acryloyloxypropyloxy)benzoic acid 2-methyl-1,4-phenylene ester;2-Methyl-1,4-phenylene bis(4-(3-(acryloyloxy)propoxy)benzoate);Benzoic acid, 4-[3-[(1-oxo-2-propenyl)oxy]propoxy]-,2-methyl-1,4-phenylene ester;4- (3-acryloyloxy-propoxy) benzoic acid 2-methyl-1,4-phenylene ester;1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenze;Benzoic acid, 4-[3-[(1-oxo-2-propen-1-yl)oxy]propoxy]-, 1,1'-(2-methyl-1,4-phenylene) ester
• CAS NO: 174063-87-7
• Molecular Formula: C₃₃H₃₂O₁₀
• Molecular Weight: 588.60118
• Mol File: 174063-87-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 733.5 °C at 760 mmHg
• Flash Point: 303.9 °C
• Appearance: /
• Density: 1.219
• Vapor Pressure: 0.003Pa at 25℃
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Water Solubility: 5.3μg/L at 20℃
• CAS DataBase Reference: 1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene(174063-87-7)
• EPA Substance Registry System: 1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene(174063-87-7)

Safety Data

• Hazardous Substances Data: 174063-87-7(Hazardous Substances Data)

Usage

Chemical Properties

White to Almost white powder to crystal

Application

1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene is one of numerous organic compounds composing American Elements's comprehensive catalog of life science products.

Flammability and Explosibility

Notclassified

Synthesis

The synthesis of?1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene is as follows:Stirrer, was added methanesulfonyl chloride 5.00 g (43.6 mmol) and tetrahydrofuran 10mL the reactor having a thermometer and two dropping device. Ice-cold while each by dropping a tetrahydrofuran solution 30mL of formula tetrahydrofuran solution 60mL and triethylamine 5.25g of (I-3-1) represented by the compound 12.9g (44.1 mmol) of (51.9 mmol) from device (equation (solution of the compound represented by I-3-1)) :( triethylamine solution) = 2: were added dropwise simultaneously with one of the drip rate.After stirring for 1 hour while cooling with ice, it was added 4-dimethylaminopyridine 2.64 g (21.6 mmol) and 2- (4-hydroxyphenyl) ethanol 2.69 g (19.4 mmol).With ice-cooling was added dropwise triethylamine 5.25g (51.9 mmol).After stirring for 7 hours, the solvent was distilled off and treated added for liquid separation dichloromethane and 5% hydrochloric acid.After the organic layer was washed with brine neutralization, and purified by column chromatography (silica gel) and reprecipitated (dichloromethane / methanol) to give the compound 12.2g of formula (I-3).82% yield, had a purity of 99.63%.

Upstream product

• 245349-46-6 4-(3-acryloyloxypropyloxy)benzoic acid 
• 95-71-6 2-methylbenzene-1,4-diol 

Relevant articles and documents

Compound

PROBLEM TO BE SOLVED: To provide a method for producing a compound having an ester bond and/or amide bond, with a small content of impurities in high yield; and to provide a high purity compound obtained by the method.SOLUTION: There is provided a method for producing a mixed acid anhydride (4) by adding a compound (1) having at least one carboxy group and a base (2) simultaneously without mixing in advance to an acid halide compound (3) to react them. Also a method for producing an ester compound and/or amide compound (6) is provided which comprises: adding a compound (1) having at least one carboxy group and a base (2) simultaneously without mixing in advance to an acid halide compound (3) to react them to produce a mixed acid anhydride (4); and thereafter reacting with a compound (5) having at least one group selected from a hydroxy group, mercapto group and/or amino group.