17478-66-9

Basic information

• Product Name: Diazene, (3-methylphenyl)phenyl-
• CAS NO: 17478-66-9
• Molecular Formula: C13H12N2
• Molecular Weight: 196.252
• Mol File: 17478-66-9.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Diazene, (3-methylphenyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Diazene, (3-methylphenyl)phenyl-(17478-66-9)
• EPA Substance Registry System: Diazene, (3-methylphenyl)phenyl-(17478-66-9)

Safety Data

• Hazardous Substances Data: 17478-66-9(Hazardous Substances Data)

Upstream product

• 15795-43-4 N-Sulfinyl-m-toluidin 
• 100-65-2 N-Phenylhydroxylamine 
• 99-08-1 1-methyl-3-nitrobenzene 
• 62-53-3 aniline 
• 586-96-9 Nitrosobenzene 
• 108-44-1 1-amino-3-methylbenzene 
• 620-25-7 N-(3-methylphenyl)hydroxylamine 
• 222851-56-1 N-phenylsulfinylamine 
• 74-88-4 methyl iodide 
• 626-01-7 3-Iodoaniline 
• 621-25-0 1-phenyl-2-(m-tolyl)hydrazine 
• 1142-13-8 2-methyl-4-phenylazo-aniline 
• 56-23-5 tetrachloromethane 

Downstream Products

• 7149-75-9 3-methyl-4-chloroaniline 
• 621-25-0 1-phenyl-2-(m-tolyl)hydrazine 
• 92022-23-6 (4-bromo-3-methyl-phenyl)-phenyl-diazene 
• 14474-22-7 3-phenylazobenzoic acid 
• 108-44-1 1-amino-3-methylbenzene 
• 59557-54-9 [Ru(C6H4N:NC6H4Me-m)(η-C5H5)(PPh3)] 
• 59568-96-6 [Ru(C6H3Me-m-N:NPh)(η-C5H5)(PPh3)] 
• 96178-63-1 N,N'-dibenzylidene-2-methyl-benzidine 
• 13924-69-1 2-methyl-N,N'-disalicylidene-benzidine 
• 62-53-3 aniline 
• 68110-75-8 Mn(N₂C₁₂H₈CH₃)(CO)4 
• 37790-12-8 (E)-1-phenyl-2-(m-tolyl)diazene 
• 68110-76-9 (C₅H₅)Pd(C₆H₄N₂C₆H₄CH₃) 
• 68110-77-0 Pd(N₂C₁₂H₈CH₃)(C₅H₅) 

Relevant articles and documents

TEMPO catalyzed oxidative dehydrogenation of hydrazobenzenes to azobenzenes

A metal-free direct oxidative dehydrogenation approach for the synthesis of azobenzenes from hydrazobenzenes has been developed by using TEMPO as an organocatalyst for the first time. The reaction proceeded in open air under mild reaction conditions. A wide range of hydrazobenzenes readily undergo dehydrogenation to give the corresponding azobenzenes in excellent yields.

Photocatalyzed oxidative dehydrogenation of hydrazobenzenes to azobenzenes

Visible light mediated oxidative dehydrogenation of hydrazobenzenes under an ambient atmosphere using an organic dye as a photocatalyst was reported for the first time. The reaction provides an environmentally benign method for the preparation of azobenzenes in excellent yields with good functional group tolerance.

Photocatalysis Enabling Acceptorless Dehydrogenation of Diaryl Hydrazines at Room Temperature

Aromatic azo compounds are privileged structural motifs, and they exhibit a myriad of pharmaceutical as well as industrial applications. Here, we report a catalytic acceptorless dehydrogenation of diarylhydrazine derivatives to access a wide variety of aryl-azo compounds with the removal of molecular hydrogen as the sole byproduct. This distinctive reactivity has been achieved under dual catalytic conditions by merging the visible-light active [Ru(bpy)3]2+ as the photoredox catalyst and Co(dmgH)2(py)Cl as the proton-reduction catalyst. The reaction proceeds smoothly under very mild and benign conditions and operates at ambient temperature. This dual catalytic approach is highly compatible with many different functional groups and has a broad substrate scope. We have also demonstrated the reversible hydrogen storage and release phenomenon on hydrazobenzene/azobenzene couple to show the utility of these compounds as hydrogen storage materials. Further diversification of azobenzene was shown by a transition-metal-catalyzed azo-group-directed ortho-C-H bond functionalization.