176689-84-2Relevant articles and documents
Synthesis, crystal structure, bovine serum albumin binding studies of 1,2,4-triazine based copper(I) complexes
Pathaw, Larica,Khamrang, Themmila,Kathiravan, Arunkumar,Velusamy, Marappan
, (2020/02/11)
A series of new copper complexes have been synthesized and completely characterized by pivotal analytical techniques. The coordination geometry around copper(I) complex was best described as distorted tetrahedral geometry. The binding of bovine serum albumin with Cu(I) complexes are also been investigated. The Stern–Volmer analysis on quenching data exhibits the presence of the static quenching mechanism. The binding constants were calculated using modified Stern-Volmer, Lineweaver–Burk and Scatchard plots. All the complexes exhibit the binding constants in the order of 104. Thus, these results can contribute to the development of Cu(I) based drugs.
A Modular Class of Fluorescent Difluoroboranes: Synthesis, Structure, Optical Properties, Theoretical Calculations and Applications for Biological Imaging
Bachollet, Sylvestre P. J. T.,Volz, Daniel,Fiser, Béla,Münch, Stephan,R?nicke, Franziska,Carrillo, Jokin,Adams, Harry,Schepers, Ute,Gómez-Bengoa, Enrique,Br?se, Stefan,Harrity, Joseph P. A.
, p. 12430 - 12438 (2016/08/24)
Ten borylated bipyridines (BOBIPYs) have been synthesized and selected structural modifications have been made that allow useful structure–optical property relationships to be gathered. These systems have been further investigated using DFT calculations and spectroscopic measurements, showing blue to green fluorescence with quantum yields up to 41 %. They allow full mapping of the structure to determine where selected functionalities can be implemented, to tune the optical properties or to incorporate linking groups. The best derivative was thus functionalised with an alkyne linker, which would enable further applications through click chemistry and in this optic, the stability of the fluorophores has been evaluated.
