17888-63-0Relevant articles and documents
Polystyrene-gallium trichloride complex: A mild, highly efficient, and recyclable polymeric lewis acid catalyst for chemoselective silylation of alcohols and phenols with hexamethyldisilazane
Rahmatpour, Ali,Vakili, Ali,Azizian, Setare
, p. 443 - 451 (2013/12/04)
Polystyrene-supported gallium trichloride (PS/GaCl3) as a highly active and reusable heterogeneous Lewis acid effectively activates hexamethyldisilazane (HMDS) for the efficient silylation of alcohols and phenols at room temperature. In this he
Mild and efficient silylation of alcohols and phenols with HMDS using Bi(OTf)3 under solvent-free condition
Kadam, Santosh T.,Kim, Sung Soo
experimental part, p. 2562 - 2566 (2009/12/24)
A very efficient and mild silylation of alcohols and phenols with hexamethyldisilazane (HMDS) at rt is developed using Bi(OTf)3 as the catalyst. Primary, secondary and tertiary alcohols as well as phenols are excellently converted into correspo