17931-55-4Relevant articles and documents
Coll et al.
, p. 7092,7093, 7098 (1972)
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Peters,J.A. et al.
, p. 349 - 351 (1977)
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A Practical Synthesis of Bicyclononan-9-one
Taeschler, C.,Sorencen, T. S.
, p. 5704 - 5705 (1998)
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Reaction of Thioketones with Carbonyl Oxides and 3,3-Dimethyl-1,2-dioxirane. Cycloaddition vs. Oxygen Atom Transfer
Tabuchi, Toshihiko,Nojima, Masatomo,Kusabayashi, Shigekazu
, p. 3043 - 3046 (2007/10/02)
The ozonolysis of vinyl ethers 1a, b in the presence of adamantane-2-thione 4a and bicyclononan-9-thione 4b gave in each case the corresponding thioozonides 5a-c in moderate yields, whilst ozonolysis of a mixture of vinyl ethers 1a-d and thiobenzophenone derivatives 4f-h gave the corresponding thione S-oxides 8f-h in isolated yields of 10-40percent, together with the benzophenones 7f-h. 3,3-Dimethyl-1,2-dioxirane, generated in situ from the reaction of acetone and 'oxone' (2KHSO5-KHSO4-K2SO4), transferred an oxygen atom to compounds 4a, f, g, i providing the thione S-oxides 8a, f, g, i in 29-97 percent yield.
Cyanidation Products of Organoboranes Derived from Linalyl Acetate
Murphy, Roger,Prager, Rolf H.
, p. 143 - 150 (2007/10/02)
The seven-membered cyclic borane obtained from the reaction of linalyl acetate and thexylborane loses 2,3-dimethylbut-2-ene, and the resulting dialkulborane gives an alcohol on treatment with sodium syanide, followed by trifluoroacetic anhydride and oxidation.The structure is confirmed by synthesis.The generality of this reaction was investigated but, of the dialkylboranes examined, only 9-borabicyclononane participated in the cyanidation procedure.A simple synthesis of menthone is presented
