18105-64-1 Usage
General Description
TRI-T-BUTOXYCHLOROSILANE is a colorless, clear, flammable liquid chemical compound with the formula C12H27ClO3Si. It is commonly used as a reagent in organic synthesis and as a precursor for the production of various silicone-based materials. TRI-T-BUTOXYCHLOROSILANE is highly reactive and reacts violently with water and air, producing toxic fumes of hydrogen chloride gas. It is also corrosive to metals and can cause severe skin and eye irritation upon contact. TRI-T-BUTOXYCHLOROSILANE should be handled with extreme caution and under strictly controlled conditions to prevent accidents and exposure.
Check Digit Verification of cas no
The CAS Registry Mumber 18105-64-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,1,0 and 5 respectively; the second part has 2 digits, 6 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 18105-64:
(7*1)+(6*8)+(5*1)+(4*0)+(3*5)+(2*6)+(1*4)=91
91 % 10 = 1
So 18105-64-1 is a valid CAS Registry Number.
InChI:InChI=1/C12H27ClO3Si/c1-10(2,3)14-17(13,15-11(4,5)6)16-12(7,8)9/h1-9H3
18105-64-1Relevant articles and documents
Facile Synthesis of Unsymmetrical Trialkoxysilanols: (RO)2(R′O)SiOH
Docherty, Scott R.,Estes, Deven P.,Copéret, Christophe
, (2018)
Trialkoxysilanols, (RO)3SiOH, are useful as ligands in transition-metal complexes because they provide models for silica-supported metal sites or precursors for the thermolytic precursor approach. However, their synthesis is mostly limited to symmetrical ones, where all RO ligands are the same. However, unsymmetrically substituted trialkoxysilanols could offer significant advantages over their symmetrical counterparts by facilitating crystallization of complexes, lowering crystallographic disorder, changing the thermal properties of the complexes made, and making the addition of pendant functional groups possible. Herein, a simple, general synthetic procedure yielding unsymmetrical trialkoxysilanols (RO)2(R′O)SiOH is presented using imidazole as a promoter.